Illuminate by Orbital (Short Version on Work 1989-2002) always makes the hairs on the back of my neck stand up, though there's loads of others too.
My best mate loved it the first time he heard it too. I've got great memories of being sat on a cliff in Torquay with him on my wedding day (he was my best man), dressed up to the nines and having a tinnie with it pumping out of the car stereo.