Fragrance Terms

Anise/Star Anise/Licorice

Anise
(Pimpinella anisum, known as anisum vulgare), sometimes called sweet cumin, has a unique aroma that is easily recognized in fragrances. It has been described as sweet, warm, and soft, yet very strong. Its fruit, from which anise oil is extracted for perfumery, is called aniseed.

The name 'anise' is derived via Old French from the Latin word anisum or the Greek anison, referring to dill. Anise is an herbaceous annual plant related botanically to carrots, tarragon, fennel, dill, cumin, caraway, and other members of the Apiaceae (parsley) or Umbelliferae family. It grows to a height of 3-4 feet. The leaves at the base of the plant are simple, 1/2-2 inches long, and shallowly lobed, while leaves higher on the stems are feathery pinnate, divided into numerous small leaflets. The flowers are either white or yellow, about 1/8 inch in diameter, and produced in dense umbels (distinctive flower clusters in which stalks of nearly equal length spring from a common center and form a flat or curved surface). The aniseed fruit is an oblong dry schizocarp (splitting into single-seeded parts when ripe).
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As with all spices, the composition of anise varies considerably with origin and cultivation method. Anise products typically contain more than 0.2ml volatile oil per 100g of spice. The essential oil is obtained by steam distillation or supercritical carbon dioxide extraction of the seeds, producing a yellow to nearly colorless liquid. The yield of essential oil is influenced by the growing conditions and extraction process, with supercritical extraction being more efficient. Regardless of the method of isolation, the main component (80-90%) of the oil is anethole, which produces the characteristic odor and flavor. Anethole (also known as anise camphor) is an organic derivative of phenylpropene, a type of aromatic compound that occurs widely in nature. In additon to contributing a large component of the odor and flavor of anise, star anise, and fennel, it also is present in anise myrtle (Myrtaceae), licorice plants (Fabaceae), camphor, and magnolia blossoms.

Anethole has been extracted in the laboratory from anise and fennel since the Renaissance, initially by alchemists. It was first investigated clinically by the Swiss chemist Nicolas-Théodore de Saussure in 1820. In 1832 the French chemist Jean Baptiste Dumas determined that the crystallizable components of anise oil and fennel oil were identical, and he determined anethole's empirical formula. And in 1845, the French chemist Charles Gerhardt coined the term anethole — from the Latin anethum (anise) + oleum (oil).

The plant is native to Greece, Egypt, and southwest Asia but is now also grown extensively in Spain and the West Indies. Anise was first cultivated in Egypt and the Middle East about 4000 years ago. Romans cooked it into little flavored cakes called mustaceoe that were served at the end of feasts, and it may have been used in Biblical times for paying tithes and taxes. It was used in Greece as a cure for insomnia, chewed in the morning to freshen the breath, and mixed with wine as a remedy for asp bites. In Turkish folk medicine, its seeds have been used as an appetite stimulatant, a tranquilizer, and a diuretic. By the 19th century it was brought to Europe for use in medicinal products, either in small doses as aqua anisi ('Water of Anise') or larger doses as spiritus anisi ('Spirit of Anise'), and including digestives and carminatives (flatulence reducers). It has been used in several cultures to treat helminthic, nematodal, bacterial, fungal, and yeast infections. Anise still is taken as a digestive after meals in parts of Pakistan and India.

Anise also finds uses in flavoring foods and drinks in many cultures. The leaves and seeds, whole or ground, are used alone or in combination with other herbs in preparation of teas and tisanes, as well as in curries, seafood dishes, alcoholic beverages (in which its slight solubility in water but high solubility in ethanol causes certain anise-flavored liqueurs to become opaque when diluted with water, the 'ouzo effect'), breads, cakes, and candies and other sweets. It is used in the United States in some root beers, such as Virgil's.

Anise is used on fishing lures to attract fish, and fishermen and hunters use anise soap to mask human scents from their hands. Builders of steam locomotives in Britain incorporated capsules of aniseed oil into white metal plain bearings so that the distinctive smell would give warning in case of overheating. And anise is a natural food plant for the larvae of some species of butterflies and moths, despite its potent fumigant insecticidal and repellant properties. Anethole is an inexpensive chemical precursor for paramethoxyamphetamine (PMA), a designer drug of the amphetamine class, and is used in its clandestine manufacture.

In perfumery, anise often is combined with vanilla, spices, musk, woods, florals, and earthy scents. It sometimes is presented as the dominant note but most often as a subtle minor one.

Masculine fragrances featuring anise:
l'Aqua di Fiori U.Man XS
Instituto Espanol Aire de Barcelona
Nickel Ull Lala
X-Bond Orange
Kenzo Air
Zara Scent #2
Chanel Allure pour Homme
Givenchy Pi
Sigilli Pyrgos
Benetton Cumbia Colors Man
l'Instant de Guerlain pour Homme
Axe Shock
Azzaro pour Homme
Cereus No. 11
Lavoisier Lider Black
Brut Black (Brut Titan)
Crabtree & Evelyn Black Absinthe
Emper Elegante
Ligne St. Barth Homme
Arran Lochranza
Yves St. Laurent La Nuit de l'Homme
Ralph Lauren Chaps Musk
Roger & Gallet Open White
Herrera 212 VIP Black
DKNY Energy for Men
Mugler B*Men
Antony One Black
Versace Blue Jeans
Claiborne Curve Wave
Michael Jordan Legend
Marc Joseph for Men
Aramis Tuscany per Uomo


Star anise (Illicium verum, meaning 'true enticement'), unrelated to anise, is a spice plant indigenous to northeast Vietnam and China and now also cultured in Japan and areas of Southeast Asia. It grows as a small- to medium-sized evergreen tree, a member of the magnolia family with dark green leaves. It produces tiny flowers followed by the distinctive star-shaped fruit with (generally) eight points, each point containing a seed. The fruits are harvested just before ripening, when the essential oil content is highest. Sun-dried, the whole fruit and seeds can be used as flavorings, and both can be ground. It is the dominant flavor in Chinese 'five-spice powder.' It has been used widely in Asia to flavor pork and chicken, in teas, and as a table seasoning, and it is a major ingredient in phở, a Vietnamese noodle soup. It is used in French mulled wine called vin chaud (hot wine), and it deepens and enriches the flavor of coffee when steeped in it. In the West it also is used to enhance the flavor of meats. As with aniseed, the flavor comes primarily from anethole oil, but the flavor of star anise is considered to be stronger and more bitter than aniseed.
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The ornamental tree is often grown for its appearance, scented flowers, and fragrant leaves. In French it is known as La Badiane. Star anise is said to ward off the 'evil eye,' bring good luck in money and love matters, and give clarity to health matters in the form of visions. Whole dried pods can be placed near one's bed for protection, purification, and prevention of nightmares. The powdered bark of the tree is used in incense in Japanese temples, and the trees are planted around temples and on graves for consecration and protection. The fruit has been used in Oriental medicine for over 3,000 years for its stimulating effect on digestion.

Star anise is considerably less expensive to produce commercially than anise and has gradually displaced P. anisum in Western commercial food and perfume markets, often substituted for anise or licorice in candies and oral hygiene products and becoming the predominant scent of this type in perfume products, by volume, by the 1990s.

The clear to pale yellow oil is steam-distilled from fresh or partly-dried pods. In perumery, the fragrance of star anise oil is more pungent than anise and has strong licorice tones, but is also soft, powdery, and floral. Its spiciness performs well with cardamom, bay, coriander, lavender, neroli, orange, petitgrain, mandarin, cedarwood, and rosewood.

About 90% of the world's star anise crop has been used for extraction of shikimic acid, a chemical intermediate used in the synthesis of the antiviral drug oseltamivir (Tamiflu), and Tamiflu shortages caused by the 2009 swine flu pandemic caused large star anise price increases. But by 2018, fermentation of E. coli had become the predominant manufacturing process to produce shikimic acid.

Japanese star anise (Illicium anisatum), a similar tree, is highly toxic and has caused severe neurological and inflammatory effects when used through accidental or economically motivated adulteration of star anise tea products. However, it has been used safely in Japan when burned as incense.

Masculine star anise perfume products:
Annick Goutal Mandragore
Cardin Signe Cardin for Him
Cardin Revelation
Armani Code
Armani Attitude Extreme
Azzaro Cockpit
Cerruti pour Home
Perry Ellis Male 2004
Ferrari Black Signature
l'Instant de Guerlain pour Homme Eau Extreme
Yves St. Laurent Opium pour Homme
Yves St. Laurent Rive Gauche pour Homme
Yves St. Lauarent l'Homme Libre
Paco Rabanne Ultraviolet Fluoressence for Men
l'Occitane en Provence Eau du Badian
Zileri Concept No. 18
Oriflame Embrace Him
Moschino Forever
Castelbajac Homme
Aquolina Blue Sugar
Dior Sauvage
Trumper Paisley



Licorice root (Glycyrrhiza glabra), in its true form, is intensely sweet (13 times sweeter than white sugar). But the extracted anethole itself produces the herbal, peppery, almost bitter taste associated with licorice candy. The roots are wrinkled and fibrous and have a sweet, earthy odor. They are boiled to extract the flavor and fragrance, and the water then is evaporated to produce a thick liquid extract or even a solid block that can be cut into bars and wrapped in laurel leaves.
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taSMncL.jpg


Licorice has been found in the Egyptian pyramids. Romans had it in Britain, and it has been found along Hadrian's Wall. Hannibal gave it to his elephants to chew as they crossed the Alps, and Bedouins are said to give their camels licorice to quench their thirst. Hindus have believed for centuries that it increased sexual vigor when prepared as a beverage with milk and sugar. And the Chinese, who have used it for 3,000 years, thought that eating the root gave them strength and endurance, and they prepared tea from it as a medicine. It has been employed as a sweetener and a flavoring, since it can mask unpleasant tastes and odors. In the 19th century it was introduced commercially as Sen Sen, a candy that was called a 'breath perfume' and was thought to help ease coughs and sore throats. The root also has been used in breweries to add flavor, dark color, and foam stability to dark beers. Similarly, it adds flavor to oral hygiene products, and it has been used in fire extinguishers to assist with the foaming action.

In perfumery, the distinction between licorice and anise often blurs, but classically licorice is seen as a slightly darker and warmer scent. If a perfume has the word 'reglisse' in the name, it most likely features licorice prominently. Licorice works well in fragrance preparations with leather, woods, and lavender and other herbs. Lolita Lempicka by Annick Menardo first brought licorice notes to mainstream perfumery with the eponymous perfume that combined it with violet, cherry, almond, and heliotrope. Lolita Lempicka au Masculin takes more of a fougère structure, with lavender and coumarin.

Masculine perfume products with licorice:
Joop Go Electric Heat
Oriflame Free Motion
Masaki Matsushima Very Male
Lolita Lempicka au Masculin
Givenchy Play in the City for Him
Carolina Herrera 212 Men Ice
Nina Ricci Memoire d'Homme
Alviero Martini GeoBlack Man
Azzaro Decibel
l'Atelier Boheme Rhizomes
Cereus No. 5
Cafe Black Label
Dior Fahrenheit
Verino Pure Man
Lacose Live
 
Anise/Star Anise/Licorice

Anise
(Pimpinella anisum, known as anisum vulgare), sometimes called sweet cumin, has a unique aroma that is easily recognized in fragrances. It has been described as sweet, warm, and soft, yet very strong. Its fruit, from which anise oil is extracted for perfumery, is called aniseed.

The name 'anise' is derived via Old French from the Latin word anisum or the Greek anison, referring to dill. Anise is an herbaceous annual plant related botanically to carrots, tarragon, fennel, dill, cumin, caraway, and other members of the Apiaceae (parsley) or Umbelliferae family. It grows to a height of 3-4 feet. The leaves at the base of the plant are simple, 1/2-2 inches long, and shallowly lobed, while leaves higher on the stems are feathery pinnate, divided into numerous small leaflets. The flowers are either white or yellow, about 1/8 inch in diameter, and produced in dense umbels (distinctive flower clusters in which stalks of nearly equal length spring from a common center and form a flat or curved surface). The aniseed fruit is an oblong dry schizocarp (splitting into single-seeded parts when ripe).
ZxpytG2.jpg
UTcbZl8.jpg
AUwwKme.jpg


As with all spices, the composition of anise varies considerably with origin and cultivation method. Anise products typically contain more than 0.2ml volatile oil per 100g of spice. The essential oil is obtained by steam distillation or supercritical carbon dioxide extraction of the seeds, producing a yellow to nearly colorless liquid. The yield of essential oil is influenced by the growing conditions and extraction process, with supercritical extraction being more efficient. Regardless of the method of isolation, the main component (80-90%) of the oil is anethole, which produces the characteristic odor and flavor. Anethole (also known as anise camphor) is an organic derivative of phenylpropene, a type of aromatic compound that occurs widely in nature. In additon to contributing a large component of the odor and flavor of anise, star anise, and fennel, it also is present in anise myrtle (Myrtaceae), licorice plants (Fabaceae), camphor, and magnolia blossoms.

Anethole has been extracted in the laboratory from anise and fennel since the Renaissance, initially by alchemists. It was first investigated clinically by the Swiss chemist Nicolas-Théodore de Saussure in 1820. In 1832 the French chemist Jean Baptiste Dumas determined that the crystallizable components of anise oil and fennel oil were identical, and he determined anethole's empirical formula. And in 1845, the French chemist Charles Gerhardt coined the term anethole — from the Latin anethum (anise) + oleum (oil).

The plant is native to Greece, Egypt, and southwest Asia but is now also grown extensively in Spain and the West Indies. Anise was first cultivated in Egypt and the Middle East about 4000 years ago. Romans cooked it into little flavored cakes called mustaceoe that were served at the end of feasts, and it may have been used in Biblical times for paying tithes and taxes. It was used in Greece as a cure for insomnia, chewed in the morning to freshen the breath, and mixed with wine as a remedy for asp bites. In Turkish folk medicine, its seeds have been used as an appetite stimulatant, a tranquilizer, and a diuretic. By the 19th century it was brought to Europe for use in medicinal products, either in small doses as aqua anisi ('Water of Anise') or larger doses as spiritus anisi ('Spirit of Anise'), and including digestives and carminatives (flatulence reducers). It has been used in several cultures to treat helminthic, nematodal, bacterial, fungal, and yeast infections. Anise still is taken as a digestive after meals in parts of Pakistan and India.

Anise also finds uses in flavoring foods and drinks in many cultures. The leaves and seeds, whole or ground, are used alone or in combination with other herbs in preparation of teas and tisanes, as well as in curries, seafood dishes, alcoholic beverages (in which its slight solubility in water but high solubility in ethanol causes certain anise-flavored liqueurs to become opaque when diluted with water, the 'ouzo effect'), breads, cakes, and candies and other sweets. It is used in the United States in some root beers, such as Virgil's.

Anise is used on fishing lures to attract fish, and fishermen and hunters use anise soap to mask human scents from their hands. Builders of steam locomotives in Britain incorporated capsules of aniseed oil into white metal plain bearings so that the distinctive smell would give warning in case of overheating. And anise is a natural food plant for the larvae of some species of butterflies and moths, despite its potent fumigant insecticidal and repellant properties. Anethole is an inexpensive chemical precursor for paramethoxyamphetamine (PMA), a designer drug of the amphetamine class, and is used in its clandestine manufacture.

In perfumery, anise often is combined with vanilla, spices, musk, woods, florals, and earthy scents. It sometimes is presented as the dominant note but most often as a subtle minor one.

Masculine fragrances featuring anise:
l'Aqua di Fiori U.Man XS
Instituto Espanol Aire de Barcelona
Nickel Ull Lala
X-Bond Orange
Kenzo Air
Zara Scent #2
Chanel Allure pour Homme
Givenchy Pi
Sigilli Pyrgos
Benetton Cumbia Colors Man
l'Instant de Guerlain pour Homme
Axe Shock
Azzaro pour Homme
Cereus No. 11
Lavoisier Lider Black
Brut Black (Brut Titan)
Crabtree & Evelyn Black Absinthe
Emper Elegante
Ligne St. Barth Homme
Arran Lochranza
Yves St. Laurent La Nuit de l'Homme
Ralph Lauren Chaps Musk
Roger & Gallet Open White
Herrera 212 VIP Black
DKNY Energy for Men
Mugler B*Men
Antony One Black
Versace Blue Jeans
Claiborne Curve Wave
Michael Jordan Legend
Marc Joseph for Men
Aramis Tuscany per Uomo


Star anise (Illicium verum, meaning 'true enticement'), unrelated to anise, is a spice plant indigenous to northeast Vietnam and China and now also cultured in Japan and areas of Southeast Asia. It grows as a small- to medium-sized evergreen tree, a member of the magnolia family with dark green leaves. It produces tiny flowers followed by the distinctive star-shaped fruit with (generally) eight points, each point containing a seed. The fruits are harvested just before ripening, when the essential oil content is highest. Sun-dried, the whole fruit and seeds can be used as flavorings, and both can be ground. It is the dominant flavor in Chinese 'five-spice powder.' It has been used widely in Asia to flavor pork and chicken, in teas, and as a table seasoning, and it is a major ingredient in phở, a Vietnamese noodle soup. It is used in French mulled wine called vin chaud (hot wine), and it deepens and enriches the flavor of coffee when steeped in it. In the West it also is used to enhance the flavor of meats. As with aniseed, the flavor comes primarily from anethole oil, but the flavor of star anise is considered to be stronger and more bitter than aniseed.
xeaY6kh.jpg
DKWtkrM.jpg


The ornamental tree is often grown for its appearance, scented flowers, and fragrant leaves. In French it is known as La Badiane. Star anise is said to ward off the 'evil eye,' bring good luck in money and love matters, and give clarity to health matters in the form of visions. Whole dried pods can be placed near one's bed for protection, purification, and prevention of nightmares. The powdered bark of the tree is used in incense in Japanese temples, and the trees are planted around temples and on graves for consecration and protection. The fruit has been used in Oriental medicine for over 3,000 years for its stimulating effect on digestion.

Star anise is considerably less expensive to produce commercially than anise and has gradually displaced P. anisum in Western commercial food and perfume markets, often substituted for anise or licorice in candies and oral hygiene products and becoming the predominant scent of this type in perfume products, by volume, by the 1990s.

The clear to pale yellow oil is steam-distilled from fresh or partly-dried pods. In perumery, the fragrance of star anise oil is more pungent than anise and has strong licorice tones, but is also soft, powdery, and floral. Its spiciness performs well with cardamom, bay, coriander, lavender, neroli, orange, petitgrain, mandarin, cedarwood, and rosewood.

About 90% of the world's star anise crop has been used for extraction of shikimic acid, a chemical intermediate used in the synthesis of the antiviral drug oseltamivir (Tamiflu), and Tamiflu shortages caused by the 2009 swine flu pandemic caused large star anise price increases. But by 2018, fermentation of E. coli had become the predominant manufacturing process to produce shikimic acid.

Japanese star anise (Illicium anisatum), a similar tree, is highly toxic and has caused severe neurological and inflammatory effects when used through accidental or economically motivated adulteration of star anise tea products. However, it has been used safely in Japan when burned as incense.

Masculine star anise perfume products:
Annick Goutal Mandragore
Cardin Signe Cardin for Him
Cardin Revelation
Armani Code
Armani Attitude Extreme
Azzaro Cockpit
Cerruti pour Home
Perry Ellis Male 2004
Ferrari Black Signature
l'Instant de Guerlain pour Homme Eau Extreme
Yves St. Laurent Opium pour Homme
Yves St. Laurent Rive Gauche pour Homme
Yves St. Lauarent l'Homme Libre
Paco Rabanne Ultraviolet Fluoressence for Men
l'Occitane en Provence Eau du Badian
Zileri Concept No. 18
Oriflame Embrace Him
Moschino Forever
Castelbajac Homme
Aquolina Blue Sugar
Dior Sauvage
Trumper Paisley



Licorice root (Glycyrrhiza glabra), in its true form, is intensely sweet (13 times sweeter than white sugar). But the extracted anethole itself produces the herbal, peppery, almost bitter taste associated with licorice candy. The roots are wrinkled and fibrous and have a sweet, earthy odor. They are boiled to extract the flavor and fragrance, and the water then is evaporated to produce a thick liquid extract or even a solid block that can be cut into bars and wrapped in laurel leaves.
k9lfKuX.jpg
taSMncL.jpg


Licorice has been found in the Egyptian pyramids. Romans had it in Britain, and it has been found along Hadrian's Wall. Hannibal gave it to his elephants to chew as they crossed the Alps, and Bedouins are said to give their camels licorice to quench their thirst. Hindus have believed for centuries that it increased sexual vigor when prepared as a beverage with milk and sugar. And the Chinese, who have used it for 3,000 years, thought that eating the root gave them strength and endurance, and they prepared tea from it as a medicine. It has been employed as a sweetener and a flavoring, since it can mask unpleasant tastes and odors. In the 19th century it was introduced commercially as Sen Sen, a candy that was called a 'breath perfume' and was thought to help ease coughs and sore throats. The root also has been used in breweries to add flavor, dark color, and foam stability to dark beers. Similarly, it adds flavor to oral hygiene products, and it has been used in fire extinguishers to assist with the foaming action.

In perfumery, the distinction between licorice and anise often blurs, but classically licorice is seen as a slightly darker and warmer scent. If a perfume has the word 'reglisse' in the name, it most likely features licorice prominently. Licorice works well in fragrance preparations with leather, woods, and lavender and other herbs. Lolita Lempicka by Annick Menardo first brought licorice notes to mainstream perfumery with the eponymous perfume that combined it with violet, cherry, almond, and heliotrope. Lolita Lempicka au Masculin takes more of a fougère structure, with lavender and coumarin.

Masculine perfume products with licorice:
Joop Go Electric Heat
Oriflame Free Motion
Masaki Matsushima Very Male
Lolita Lempicka au Masculin
Givenchy Play in the City for Him
Carolina Herrera 212 Men Ice
Nina Ricci Memoire d'Homme
Alviero Martini GeoBlack Man
Azzaro Decibel
l'Atelier Boheme Rhizomes
Cereus No. 5
Cafe Black Label
Dior Fahrenheit
Verino Pure Man
Lacose Live
Once again thank you John , for taking the time to write this , very informative.
 
Thank you for all the time you have taken to think and write this most informative insight in to the art of perfumery. As end users we don't fully appreciate the knowledge and skills which give us these wonderful scents

Great stuff
 
Essential Oil vs. Fragrance Oil

There can be some confusion about the differences between essential oils (EOs) and fragrance oils (FOs) used in perfume products. Most simply, EOs are extracts derived from plants and FOs are synthetic chemical scent compounds. Generally, EOs can be used for scenting, flavoring, or healing applications (in aromatherapy), while FOs are used in foods or candies for flavor but are mainly used for their scent qualities. FOs are ubiquitous in commercial cleaning products, room air fresheners, personal care products (including hand sanitizers, toilet paper, and tampons), laundry soap, baby diapers, stationary, foods and drinks, toys, and other products. Hand, face, and body soaps and other skin care products, as well as candles, even items labeled 'natural,' often contain FOs. It is common for a label to say 'contains essential oils' when the item also contains fragrance oils, which contributes to misunderstanding.

Essential Oil (EO)

Essential oils are concentrated hydrophobic liquids containing naturally occurring volatile (easily evaporated at room temperature) chemical compounds. They are derived from different parts of a plant, including blossoms, fruits, seeds, leaves, roots, stems, barks, woods, or resins. Generally they are not manipulated significantly, processed, or diluted with a carrier oil or other additives (except for dilution in aromatherapy) before use. They can also be known as volatile oils, ethereal oils, or aetherolea, or simply as the oil of the plant from which they were extracted, such as 'oil of clove.' An EO is considered essential in the sense that it contains the 'essence' of a plant's fragrance. The term essential does not mean indispensable to a living organism the way it does with the terms essential amino acid or essential fatty acid.

Some plants, like bitter orange, can be sources for several different types of EO.

EOs generally are extracted by distillation, usually with steam and most often single-process rather than fractional; but they also can be obtained by cold pressure expression, solvent extraction, sfumatura (mechanical folding), absolute oil extraction, and wax embedding. Most of the common oils, such as lavender, peppermint, tea tree, patchouli, and eucalyptus, are steam-distilled in an alembic. In single-process distillation, water is heated and its steam passes through the plant material and vaporizes the volatile compounds. The vapor flows through a coil, where it condenses back to liquid that is then collected in a receiving vessel. The recondensed water is called a hydrosol, hydrolat, herbal distillate, or plant water essence. Those marketed as hydrosols include rose water, lemon balm, clary sage, and orange blossom water.

Most citrus peel oils are expressed or cold-pressed mechanically, similar to olive oil extraction, and due to the relatively large quantities of oil in citrus peel and the low cost to grow and harvest the raw materials, citrus oils are cheaper than most other EOs. They are obtained for the most part as byproducts of the citrus fruit industry. Historically, prior to the discovery of the distillation process, all EOs were extracted by pressing.

Most flowers contain too little volatile oil to undergo expression, but their chemical components are too delicate and easily denatured by the high heat of steam distillation. Instead, they are extracted with a solvent such as hexane or supercritical carbon dioxide (a fluid state of CO2 in which it is held at or above its critical temperature and critical pressure, expanding to fill its container like a gas but with a density like that of a liquid). Extracts from hexane and other hydrophobic solvents are called concretes. While highly fragrant, they are a mixture of essential oil, waxes, resins, and other oil-soluble plant materials. Usually the concrete is then chilled in an alcohol solution to cause the waxes and other lipids to precipitate out. The precipitate is filtered, and the ethanol is removed by evaporation and/or vacuum purging, leaving behind the 'absolute.'

Use of supercritical carbon dioxide as a solvent in fluid extraction avoids the presence of petrochemical residues in the product and the loss of some perfume 'top notes' that occur when steam distillation is used. The supercritical CO2 process extracts both the waxes and the essential oils, which are subsequently processed with liquid CO2 by temperature lowering under pressure. The cooling separates the waxes from the oils, and the lower temperature prevents decomposition of compounds. When the extraction is complete, pressure is reduced to ambient levels and the carbon dioxide reverts to gas, leaving no residue.

EOs are used for fragrance in perfumes, cosmetics, incense, soaps, and cleaning products, and for flavoring foods and drinks. In aromatherapy, frequently considered a form of alternative medicine and more popular again in recent decades after a period of decline, pure EOs that enter the body through the skin (via massage when mixed with a carrier oil such as jojoba, coconut, wheat germ, olive, or avocado; or via bathwater) or the nose (via volatile diffuser, burning candle or incense, or humidifier) are used to influence physical, emotional, and mental health. They are reputed to enhance mood, relieve inflammation or symptoms such as pain or fatigue, and kill body germs. However, while research continues, there is not yet much clinical evidence that they can effectively treat any specific condition.

Each EO component can have both positive and negative effects either topically or internally, depending upon its particular properties and concentration, and can be toxic. One well-known example is cinnamon oil, touted for its antiseptic and astringent capabilities yet highly irritating to some skin. Children may be particularly susceptible to the toxic effects of improper EO use, especially at high concentrations, and when the oils are swallowed. EOs also can cause immunologically-mediated allergic reactions in those allergic to the source material.

The quality of EOs can vary widely, with the quality of a given batch of oil being influenced by how the plants are grown (including use of insecticides and other chemicals), possible processing (including dilution or adulteration during extraction), packaging and handling (with exposures to heat, light, or oxygen), and storage. The usual shelf life of an EO is around 1-2 years after opening.

EOs have been used in folk medicine for centuries, with the earliest recorded mention of the techniques for EO production believed to be that of an al-Andalusian (Muslim Spain) physician-chemist, Ibn al-Baitar (1188-1248). Modern academic studies typically discuss the specific chemical compounds of which EOs are composed, such as referring to methyl salicylate rather than 'oil of wintergreen.' Medical uses of EOs, for treatment of cancers in particular, are now subject to regulation in most countries.

Finally, some EOs can act as natural pesticides against insects and arthropods, repelling, inhibiting growth or reproduction, or causing animal death at concentrations that are nontoxic for mammals. Some that have been investigated for this use include rose, lemon grass, lavender, thyme peppermint, and eucalyptus. They have been used commercially to a limited extent, and their popularity is increasing among organic farmers and environmentally conscious consumers.

EOs are typically more expensive than FOs because it is costly to plant, grow, harvest, and process the plants, although this varies with the type of oil, the season, and the availability of the product. Steam distillation, expression, and solvent extraction can be complicated and expensive, and a very large amount of plant material is required to produce even a small quantity of essential oil. For example, around 1000 rose petals are needed to make just one drop of rose EO. Citrus EOs, on the other hand, are normally cheaper because they are easier to extract. Each particular EO is comprised of between 50 and 500 different naturally occurring chemicals, which are quite difficult to reproduce synthetically and some of which have not even been identified chemically yet. In addition, depending on the season, climate, and growing conditions of a plant, the biochemical makeup - and thus the scent and/or taste - of a particular EO will vary, and it is difficult for manufacturers and crafters to keep their finished products consistent.

Commonly used EOs in perfumery include lavender, chamomile, rose, hyssop, clary sage, rosemary, ylang ylang, myrrh, vetiver, frankincense, grapefruit, peppermint, spearmint, wintergreen, basil, orange, melaleuca (tea tree), lemon , cassia, and oregano.

Fragrance Oil (FO)

Fragrance oils are artificially manufactured compounds (or natural EOs that have been diluted with a carrier such as propylene glycol, vegetable oil, or mineral oil) created in a laboratory and specifically designed to mimic naturally occurring scents or to invoke a feeling (such as 'spring rain') or emotion. They are also known as aroma oils, aromatic oils, or flavor oils.

The range of FO scents is enormous, and generally they are relatively inexpensive. They are used primarily in the manufacture of perfumes, cosmetics, and flavorings. For reasons of animal cruelty or because of animal population decreases and endangerment, historically popular perfume fragrance notes such as civet, musk, ambergris and castoreum, derived from animals through processes that typically mistreat or kill the animals that create the scent sources, now have been replaced in large part by synthetic versions or products naturally derived from plants producing similar fragrances.

FOs seem to be problematic more often than EOs in personal care products because they can be drying and more irritating to the skin in concentrations commonly used, and they are thought to be capable of causing many other potentially serious health problems. They often are less desirable than plant-derived EOs for allergic or otherwise sensitive people, commonly causing headaches, dizziness, rashes, coughing, nausea and voming, and skin irritation. In official terms of being health hazards, a synthetic version of the same chemical compound as in a natural EO is usually deemed comparable. Recent studies of FOs have suggested 'possible mutagenic and genotoxic effects' and hormone disruptions that are linked to abnormal cell reproduction and tumor growth.

'Natural' vs. Synthetic Fragrance Oils

There is a difference between 'natural' and totally synthetic types of FOs. 'Natural' FOs are made in a laboratory but are created by isolating aromatic components from a naturally occurring complex complete scent. There is debate about whether they can be considered truly natural, since they are still created by human science although derived from a natural source. Totally synthetic FOs are created with chemical compounds that do not exist in nature, often composed of petroleum by-products, which makes them cheap and versatile. Many commercial scent products are made with synthetic fragrances because they retain their aromas for longer periods of time than natural oils. Manufacturers sometimes will market their FOs with midleading names such as 'pikake oil' or 'plumeria oil,' which actually are simply synthetic oils infused with a small amount of exract from the actual flowers. This is true especially with floral scents like cherry blossom or freesia, fruit scents like peach, watermelon, or banana, and scents with names that sound 'natural' such as 'white rain.'

Commonly used fragrance oils in perfumery include ylang ylang, vanilla, sandalwood, cedarwood, mandarin orange, cinnamon, lemongrass, rosehip, and peppermint.

Mixing Essential Oils and Fragrance Oils

Generally EOs and FOs mix well if you wish to combine them. Rather than shaking the mixture, the bottle should be warmed between the hands and then gently rolled on a table or tipped upside down a few times. Any mixture should be left in a cool, shaded area for a week for all the initial components to blend well before it is used or tweaked again.
 
Frankincense

Frankincense, also known as olibanum (or Levonah, Luban, Khunk), is an aromatic, congealed, resinous sap obtained from trees of the genus Boswellia in the family Burseraceae. The name comes from the Old French encens ('high-quality incense'); the word franc meant 'noble' or 'pure.' Its other name, olibanum, comes from the Arabic al-luban ('that which results from milking'), possibly a reference to the milky resin.
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True frankincense comes from five main species, the purest from Boswellia sacra. The gum resin is produced under the bark of small tree shrubs that grow in limestone-rich rocky outcrops, cliffs, or dried riverbeds of Southern Arabia (the Dhofar region of Oman and Yemen), India, and Northern Africa (Somalia, Ethiopia, Eritrea, and Kenya). It sometimes sprouts even on solid rock by means of attachment by a bulbous disk-like swelling of the trunk. (This feature is slight or absent in trees that grow in less stormy areas or in rocky soil or gravel.) The plants obtain moisture from morning mist. Trees begin to produce resin at about 8-10 years of age. The resin is harvested by striping (making incisions in the bark) and then allowing the exuded resin to bleed out and dry for about a week into streaks called tears before being cut off as hardened crystal and then hand-sorted for quality. The longer it is left on the tree, the harder it becomes. Striping or tapping is usually done twice a year (spring and fall), with the final tap generally producing the best resin due to its higher content of aromatic terpene, sesquiterpene, and diterpene. Differences in soil and climate create even more diversity of the resin. It is graded by quality based on aroma, purity, color, age, and shape, with the first, lowest grade being the most common. This grade is brownish and has many bark particles in it. The highest grades are called Silver and Jojari. Most of the annual harvest comes from Somalia and India, and the finest resin is said to come from Somalia and Djibouti, where the Roman Catholic Church purchases most of its stock for incense.
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The dried resin is crushed to a powder, put into an oil bath, and steam distilled to produce the essential oil. Content of essential oil in the resin is about 8%. The distilled liquid is pale yellow-brown to green and has a very strong aroma.
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Frankincense tree populations appear to be declining gradually, partly due to over-exploitation by populations with few other sources of income, which decreases germination rates. In addition, burning, grazing, insect attacks, destruction in armed conflict, and conversion of frankincense woodlands to food agriculture in poverty-stricken areas are decreasing the numbers of trees. In 1998, the International Union for Conservation of Nature warned that Boswellia sacra was 'near threatened,' and a 2006 ecological study demonstrated that Boswellia trees were becoming more difficult to find. A 2019 study predicted a 50% reduction in some Boswellia species within two decades.

Popular folk etymology suggests a connection with the Franks (especially Frankish Crusaders), who reintroduced the spice to Western Europe during the Middle Ages. Frankincense has been traded on the Arabian Peninsula and used in religious ceremonies for thousands of years (and named in Christianity as one of the three gifts from the Magi to the infant Jesus). Some of it was traded as far as China. The Greek historian Herodotus noted that frankincense resin was dangerous to harvest because of venemous snakes that lived in the trees, and he described an Arabian method of burning the gum of the styrax (snowbell) tree to produce smoke that drove the snakes away.

In perfumery, the odor profile is sweet, balsamic, somewhat green, warm, woody, and spicy with a hint of citrus and a piney undertone. Initially it is reminiscent of freshly ground black pepper with a lemon peel twist, and as it dries down it reveals its woody character, both rich and crisp, with a dark, balsamic finish. With both cold and warm elements, it is quite versatile. It is associated often with Oriental and heavy, dark fragrances, especially those with amber, cedarwood, spices, vanilla, and patchouli. But it also supports and blends quite well with lighter, effervescent orange, bergamot, and green tones.

Frankincense has been used in perfume products, essential oils, cleaning products, cosmetics, pharmaceuticals, and 'natural' medicines. It is inhaled in aromatherapy or applied to the skin for its supposed health benefits, including calming, clearing, and relaxing the mind. Folk remedies include it for treatment of nausea, indigestion, cough, hypertension, depression, and anxiety. In Chinese medicine, frankincense (called ru xiang), when combined with myrrh, was thought to have antibacterial properties as well as blood-stimulant value, when used topically or orally. In Persia, it was said to be used for diabetes, gastritis, and stomach ulcers, and ancient Egyptians cleansed body cavities with frankincense and natron during the mummification process. By itself or in incense (its most common use), it has been burned in many Hebrew and Christian churches, including Eastern Orthodox, Oriental Orthodox, and Roman Catholic, partly because it is believed to aid prayer and meditation. Both Christian and Islamic faiths have mixed it with oils to anoint newborn infants and church initiates and in burial rituals. The resin powder or oil are put into potpourri, and oil and smoke from burning incense are used commonly to scent room air. In addition, the smoke is effective for driving away mosquitos, thus reducing the incidence of malaria. Finally, frankincense can be used as a flavoring agent, giving a peppery-balsamic flavor. It is added to foods, drinks, and toothpastes, and in the parts of the Middle East it is chewed as a gum to freshen the breath.

Masculine fragrances with significant frankincense:

Abercrombie & Fitch Oud Essence
Amouage Jubilation for Men
Armand Ultimate Drive
Aquaflor Firenze Azar
Armani Privé Bois D'Encens
Ashley Oud pour Lui
Aziza Dark Entity
Bvlgari Aqva Amara; Kobraa; Ambero
Caron Parfum Sacré
Comme des Garçons Incense Series Avignon
Dior Sauvage
Guerlain Arsene Lupin Dandy
Hermès Eau de Gentiane Blanche
Lise London Perfect Gentleman
Malone London Incense & Cedrat
Mauboussin Cristsal Oud
Osmo Encens Epice
Prada Infusion d'Homme
Regence Kolnisch Juchten
Sonoma Incense Pure
Tauer Incense Extreme
Zegna Passion
 
Perfume Fixative

A fixative is used to equalize the vapor pressures, and thus the volatilities, of the raw materials in a perfume oil and thus to increase their tenacity (retention of fragrance on the skin).

A misconception is that if a fragrance has more tenacity (lasts longer) it will smell stronger. A fixative may or may not affect the strength of the fragrance. If an agent increases the strength of a perfume it is called an enhancer or 'booster.' Enhancers with little scent of their own are sometimes marketed by themselves and used in layering with perfume products by consumers.

Fixatives are materials that:
1.Slow down the rate of evaporation of the more volatile materials in a perfume composition, causing only gradual changes in the aroma of the perfume as the ingredients in it fade away (during the drydown phase).
2.Lend a particular note to the perfume throughout all stages of evaporation but do not significantly affect the evaporation rate of the other materials in the perfume.
3.Improve, fortify, and/or transport the vapors or lend a combination of a diffusive or retentive effect, typically through the addition of trace amounts.
4.And perhaps are odorless or almost odorless and lend a stabilizing action by halting the odor of the low-boiling (volatile) materials in the perfume. Fixative materials that may or may not have or impart an aroma of their own to a blend. Some nonodorous fixatives are glucam P20, isopropyl palmitate, diethyl pthalate, glycerin, benzyl benzoate, PVP, hydroxyethyl cellulose. Example of fixatives with significant scents are fixolide, vanilla and vanillin, cinnamic alcohol, benzophenone, musk ketone, fixative 505, balsam of Peru, benzoin resin, tonka bean, sandalwood, amyris oil, and copaiba oil.

Fixatives may make up a small or a large percentage of the overall perfume blend depending on the technology employed and the type of fragrance being created.

The fixative qualities of an oil and its tenacity do not necessarily mean the same thing. Tenacity is the lasting effect of a perfume material and its ability to linger on the skin. An aromatic perfume ingredient may have immense tenacity but may have little impact on the evaporation rate of the other perfume ingredients with which it is combined (i.e. able to impart fixative qualities). While a botanical fixative will impart longevity and help extend the sillage of a natural perfume, in most cases it will not be as effective as a synthetic fixative.

In Piesse's 1862 Art of Perfumery, he writes that a blend of crushed orris root and rectified spirits is "never sold alone, because its odour… is not sufficiently good to stand public opinion… But in combination its value is very great… it has the power of strengthening the odour of other fragrant bodies." The Perfume Handbook, published in 1992, lists 42 separate botanicals with fixative properties.

Natural fixatives are plant resinoids/gums (e.g. frankincense, myrrh, benzoin, balsam of Peru) or low-volatility substances (e.g. vetiver, oakmoss) and animal products. Synthetic fixatives include substances of low volatility (diphenylmethane, cyclopentadecanolide, ambroxide, benzyl salicylate) and virtually odorless solvents with very low vapor pressures (benzyl benzoate, diethyl phthalate, triethyl citrate).

Some common botanical fixatives:

Ambrette
Amyris
Angelica
Balsam of Peru
Benzoin
Cedarwood (Atlas)
Cistus/Labdanum
Clary sage
Frankincense/Olibanum
Galbanum
Liquidambar (Styrax)
Myrrh
Oakmoss
Orris
Patchouli
Sandalwood
Storax
Tolu balsam
Vanilla
Vetiver
Violet Leaf

Animal product fixatives:

Ambergris
Castoreum
Civet (the only one still commonly used, since its collection does not harm the animal)
Musk
 
Oakmoss/Lichens/Mosses

Oakmoss and others mosses and lichens have been used somewhat indiscriminately in perfumery under the name 'oakmoss,' and recent changes in their commercial use driven by health regulation have stimulated more precise research and methodology and have sharply divided opinions about them among perfume manufacturers and consumers.

Oakmoss

Evernia prunastri, known as oakmoss or 'mousse de chêne in French,' is a species of lichen. It can be found in many mountainous temperate forests throughout the Northern Hemisphere, including parts of France, Portugal, Spain, North America, much of Central Europe, and North Africa. Oakmoss grows primarily on the trunk and branches of oak trees, but is also commonly found on the bark of other deciduous trees and conifers such as fir and pine. The thalli (undifferentiated plant bodies lacking a vascular system) of oakmoss are 1-3 inches in length and bushy, and they grow together on bark to form large clumps. Oakmoss thalli are flat and strap-like and are palmately branched, ending in pointed tips resembling the form of deer antlers. The upper surface is warty with pale gray reproductive bodies (soredia); the undersurface is lighter, with a faint netlike pattern. The color of oakmoss ranges from green to a greenish-white when dry and dark olive-green to yellow-green when wet. The texture of the thalli is rough when dry and rubbery when wet.
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Oakmoss is commercially harvested in countries of South-Central Europe, especially in the Balkans, and usually is exported to the Grasse region of France, where its fragrant compounds are extracted as oakmoss absolutes and extracts. It is often used as an excellent, tenacious perfume fixative, leaving the scent profiles of other constituents in the fragrance relatively unmodified, much like civet does. The scent of oakmoss forms a solid base note of many fragrances and is a key component of most fougère and chypre perfumes and some vintage vetiver formulations. It has a distinct and complex odor that can be described as woody, sharp, damp, earthy, deep, dark, slightly saline, and/or slightly sweet, depending on its concentration and its synergy with other elements in the perfume. It combines especially well with floral and green notes, and it is said to deepen and enrich the animalic component of fragrances due to a leather-like undertone that persists from the top note through the drydown. Oakmoss growing on pines has a slightly different turpentine-like odor that is valued in certain perfume compositions.

Oakmoss absolute used in perfumery is soluble in alcohol and partially soluble in fixed carrier oils. It is obtained by solvent extraction or vacuum distillation. The absolute type from solvent extraction is dark green or brown and has a stronger, natural, earthy-mossy scent with a slight leather undertone. Vacuum distillation produces a pale yellow or green one with a drier, earthy, bark-like character.

Oakmoss is among the ingredients most widely used by perfumers. An essential element of fragrances within the chypre family, especially in combination with bergamot, it ‘anchors' the more volatile notes. Oakmoss is sensual, with hints of musk and amber; the other mosses and lichens share the same general odor profile. Since Roman times in Cyprus, it was blended with styrax, calamus, and labdanum in this type of perfume in a generally unstandardized way. In the Middle Ages and then the Renaissance, oakmoss and tragacanth began to be added, and the herb mixtures were used to create ‘pastilles' for medicinal and religious burning. It has been used since the 16th century in Western European perfumery, and fragrance recipes from the 1770s list oakmoss as well as civet, ambergris, and musk. Francois Coty's Chypre perfume further popularized this type of fragrance in 1917 and it variations and descendants thereafter.

Elements in oakmoss, especially atranol, chloroatranol, and methyl-beta-orcinol carboxylate, can cause contact allergic skin reactions on people with known skin sensitization, much like poison ivy does. Oakmoss has been 'blacklisted' since 2009-2010 by the International Fragrance Association (IFRA), a body that regulates the guidelines for safe usage of chemicals and essential oils in perfumes, and its use in perfumes is now highly restricted (to no more than 0.1% of combined mosses in compositions applied to the skin). Many scents consequently have been reformulated in recent years, with other chemicals such as patchouli or synthetic imitations substituted for oakmoss. Because IFRA's member manufacturers produce more than 90% of the world's fragrances, its rules effectively function as law for nearly all companies. Chemists who have worked since around 2001 to make synthetic oakmoss 'knockoffs.' One of them, Cyrill Rolland, managed to imitate synthetically the way the scent of oakmoss seems to evolve, first evoking wet timber with a slightly bitter undertone of seaweed, and then changing to a dry, woody aroma. To untutored noses the fake products smell like the genuine oakmoss; however, there have been many complaints among more discerning consumers about the reformulated products. One prominent perfume writer even pronounced the art of fragrances "officially dead." Since perfumery is a $2 billion industry in which even a microliter substituion of one component for another can make the difference between a failure and megaseller, the limitation of oakmoss use has had a huge impact. As Guerlain's in-house perfumer Thierry Wasser explained, whenever some part is removed from an ingredient, "it leaves a hole."

Some perfumers, including Arcadi Boix Camps, have tried using patchouli, vetiver, or a synthetic 'mossy woods' note instead of oakmoss, with varying success. One example is Comme des Garcons White. Wasser's initial answer was to substitute with celery seed in the famous Guerlain chypre Mitsouko and their Parure, but subsequently he has developed a processed raw oakmoss material to mimic it without the specific molecule not allowed by the guidelines. Says perfumer Clement Gavarry, "Some ingredients are there just to wrap things up. They might add performance or make a fragrance last longer. But ingredients like oakmoss are there to provide character or give a crucial twist to the fragrance." One fragrance writer, Denyse Beaulieu, has called the reformulated fragrance type an 'iFrag,' a pun on IFRA and fragrance and a reference to the iPod, whose music she describes as "skinny and fleshless," with a seemingly accurate surface but an empty inner substance. She complains, "People want a sound bite of a fragrance — something nice, clean, and fresh" that avoids taking risks. William Troy, IFRA North America's president from 2007 to 2010, acknowledges that some essential components are sacrificed. "And you know what? We can't do otherwise," he says. "If we can't demonstrate a safe use level, it's not in our best interest to allow that material to continue to be used in a product, because there are going to be problems — image problems as well as adverse consumer reactions." Some people have suggested allowing higher concentrations of mosses provided there is a prominent printed warning on the box, while others have presented a 'quenching' hypothesis, in which the anti-inflammatory azulene, which occurs natuarlly in chamomile, would be added. However, aluzene has its own odor profile and a blue color that complicate this idea.

Recently there has been a more promising commercial answer to providing oakmoss scent: through the processes of gas chromatography-mass spectrometry analysis and fractionation – identifying and separating the different components of an individual ingredient by gradients during a phase transition, and removing the potential sensitizers – it's possible to get a substance that can be tweaked at the molecular level so that it is much closer to original whole oakmoss in its scent qualities. The company Mane, manufacturer of an increasingly popular oakmoss facsimile, claims that its natural substitute, derived from analysis of the oakmoss absolute and with a molecular structure kept as a closely guarded secet, is nearly identical in scent to oakmoss while still able to pass the IFRA tests.

Tree Moss

Pseudevernia furfuracea, commonly known as tree moss, is a lichen (or lichenized moss) that grows on the bark of 'nutrient poor' trees such as birch, pine, and spruce. This species, often somewhat carelessly included under the same common name as its botanic cousin oakmoss but growing less widely, has had numerous commercial roles, including use in perfume, Egyptian embalming, and medicine. Another species, Usnea barbata, also is used quite often in perfumery.
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Large amounts of tree moss (sometimes called fir moss), like true oakmoss, are processed in Grasse, France for the perfume industry. Its fragrance is said to be generally one-dimensional, more astringent and less complex or nuanced, and less like a 'wet forest floor,' than oakmoss. This results in a relative lack of 'fullness,' for which some perfumers try to compensate by adding other ingredients such as patchouli. Tree moss has a turpentine smell before processing. In perfumes, oakmoss softens the tartness of citruses/aledhydes with which is is mixed, providing a powdery effect (especially in conjuction with orris root), which tree moss does not give. However, tree moss can add a desirable, persistent, dry background dimension that works well in contrasting moister and richer qualities such as those of rose and tobacco absolutes. In terms of fragrance classification, tree moss may be considered to have a position somewhere between leather and oakmoss. In perfumes it also works as a fixative basically the same way as oakmoss.

Benzene extraction, which has been banned for decades from manufacturing of perfumes, produced very high-quality lichen extracts, and attempts to use other similar solvents have been only partially successful. Currently either pure hexane or mixtures of hexane with acetates (or more rarely isopropanol) are used to removed the crude resinoids from tree mosses. The resinoids are then treated further with ethanol to produce absolutes. Traditionally these processes have been performed after desiccation of the lichen, since fragrance has been thought to develop significantly during storage. The qualitative scent composition of tree moss or lichen extracts can vary widely, depending on the exact method of preparation and on the presence of any residual or environmental contaminants.

Soluble extracts from P. furfuracea var. furfuracea and var. ceratea, as well as specific individual compounds found in them, have antimicrobial activity against a variety of microorganisms. In areas of Andalucia (Spain), P. furfuracea still is used for treating infections, especially respiratory complaints. The thallus is washed and boiled for a long time to prepare a decoction which is drunk for this purpose.

Water extracts of this species have been shown to have a potent protective effect on genotoxicity caused by bismuth compounds such as colloidal bismuth subcitrate, and it has been investigated for its ability to absorb toxic heavy metals from solution. The metal-binding biosorption for copper and nickel suggests it may have potential as a biosorbent for medical treatment of heavy metal toxicity. Because P. furfuracea tends to bioaccumulate heavy metals proportional to their concentration in airborne particulates, it can be used as a monitor of air quality, although it has been noted that element accumulation is partly dependent on the hydration level of the specimen. Also, the species is sensitive to ozone concentrations, and ozone fumigation results in impairment of its metal absorption, so it can reflect ambient ozone levels. P. furfuracea has also been used to monitor the levels of radionuclides, such as those of Cesium-137 in Austria after the Chernobyl nuclear accident.

In ancient Egyptian embalming, P. furfuracea was packed into the body cavity of mummies, although it is not certain whether this was done because of the supposed preservative properties or because of its aromatic properties.

Other Lichens

Other mosses and lichens have been used for centuries in folk medicine, including for treatment of mouth ulcers, cough, diarrhea, rabies, baldness, bleeding, fungal infections, and epilepsy, and they still are used commercially as natural deodorants.

They also have been used for dying cloth, candles, and other products. In medieval Europe, lichen dyes were dissolved in human urine, and clothing yarns were immersed in the mixture to color them, with ammonium salts in the urine acting as a mordant to make the dyes permanent. Northwest Pacific native American cultures used a lichen that grows on the bark of pines and firs to make a canary-yellow dye for porcupine quills that were woven into baskets, and Bryoria lichen was used by other Amerindians to give a brown or green color to shirts and leggings. A brown dye from the lichen Permelia omphalodes is still used in modern hand-woven Harris tweeds from the Outer Hebrides.
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Certain toxic mosses have been used by Norwegians with baits to kill predatory wolves and protect their herd animal flocks, while digestible ones have provided flavoring for breads, beers (in place of hops), and salads, especially during times of famine.

'Oakmoss' as a perfume fragrance component is prominent in:

Abercrombie & Fitch 1892 Cobalt, Summer
Agua de Cheiro Saver Royal
Al Battash Concepts Ghala Zayed
Avon Wilderness, Windjammer
Azzaro Chrome Intense
Bloke Michael
Creed Aventus
Criminal Elements Ruben
Cuba Paris Green
Cuir de Russies (various)
Domenico Caraceni pour Homme
EastWest Bottlers Bluegrass
Faberlic Mon Roi
Frau Tonis Parfum No. 65 Eau de Berlin
Guerlain Mitsouko
Houbigant Fougère Royale
Jean Desses Gymkana
Jivago Red Gold
Joaquin Cortes Yekipe Pura Pasion
Juvena Lonestar
L'Artisan Parfumeur Riviera Palace
Le Prince Jardinier Arboretum
Loewe Esencia pour Homme
Luciano Soprani Uomo
LR/Racine Agent XY
Outremer Mousse de Chene-Oakmoss
Parfum Regence Oakmoss
Paris Elysees Dollar
Penhaligon Eucris
Pinaud Clubman
Pino Silvestre Muschi de Bosco
Ralph Lauren Safari
Scorpio Vertigo
Shirley May Don Carlos
Soyuzparfumerprom Diplomat
Thera Cosmeticos Zeus
 
Oakmoss/Lichens/Mosses

Oakmoss and others mosses and lichens have been used somewhat indiscriminately in perfumery under the name 'oakmoss,' and recent changes in their commercial use driven by health regulation have stimulated more precise research and methodology and have sharply divided opinions about them among perfume manufacturers and consumers.

Oakmoss

Evernia prunastri, known as oakmoss or 'mousse de chêne in French,' is a species of lichen. It can be found in many mountainous temperate forests throughout the Northern Hemisphere, including parts of France, Portugal, Spain, North America, much of Central Europe, and North Africa. Oakmoss grows primarily on the trunk and branches of oak trees, but is also commonly found on the bark of other deciduous trees and conifers such as fir and pine. The thalli (undifferentiated plant bodies lacking a vascular system) of oakmoss are 1-3 inches in length and bushy, and they grow together on bark to form large clumps. Oakmoss thalli are flat and strap-like and are palmately branched, ending in pointed tips resembling the form of deer antlers. The upper surface is warty with pale gray reproductive bodies (soredia); the undersurface is lighter, with a faint netlike pattern. The color of oakmoss ranges from green to a greenish-white when dry and dark olive-green to yellow-green when wet. The texture of the thalli is rough when dry and rubbery when wet.
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Oakmoss is commercially harvested in countries of South-Central Europe, especially in the Balkans, and usually is exported to the Grasse region of France, where its fragrant compounds are extracted as oakmoss absolutes and extracts. It is often used as an excellent, tenacious perfume fixative, leaving the scent profiles of other constituents in the fragrance relatively unmodified, much like civet does. The scent of oakmoss forms a solid base note of many fragrances and is a key component of most fougère and chypre perfumes and some vintage vetiver formulations. It has a distinct and complex odor that can be described as woody, sharp, damp, earthy, deep, dark, slightly saline, and/or slightly sweet, depending on its concentration and its synergy with other elements in the perfume. It combines especially well with floral and green notes, and it is said to deepen and enrich the animalic component of fragrances due to a leather-like undertone that persists from the top note through the drydown. Oakmoss growing on pines has a slightly different turpentine-like odor that is valued in certain perfume compositions.

Oakmoss absolute used in perfumery is soluble in alcohol and partially soluble in fixed carrier oils. It is obtained by solvent extraction or vacuum distillation. The absolute type from solvent extraction is dark green or brown and has a stronger, natural, earthy-mossy scent with a slight leather undertone. Vacuum distillation produces a pale yellow or green one with a drier, earthy, bark-like character.

Oakmoss is among the ingredients most widely used by perfumers. An essential element of fragrances within the chypre family, especially in combination with bergamot, it ‘anchors' the more volatile notes. Oakmoss is sensual, with hints of musk and amber; the other mosses and lichens share the same general odor profile. Since Roman times in Cyprus, it was blended with styrax, calamus, and labdanum in this type of perfume in a generally unstandardized way. In the Middle Ages and then the Renaissance, oakmoss and tragacanth began to be added, and the herb mixtures were used to create ‘pastilles' for medicinal and religious burning. It has been used since the 16th century in Western European perfumery, and fragrance recipes from the 1770s list oakmoss as well as civet, ambergris, and musk. Francois Coty's Chypre perfume further popularized this type of fragrance in 1917 and it variations and descendants thereafter.

Elements in oakmoss, especially atranol, chloroatranol, and methyl-beta-orcinol carboxylate, can cause contact allergic skin reactions on people with known skin sensitization, much like poison ivy does. Oakmoss has been 'blacklisted' since 2009-2010 by the International Fragrance Association (IFRA), a body that regulates the guidelines for safe usage of chemicals and essential oils in perfumes, and its use in perfumes is now highly restricted (to no more than 0.1% of combined mosses in compositions applied to the skin). Many scents consequently have been reformulated in recent years, with other chemicals such as patchouli or synthetic imitations substituted for oakmoss. Because IFRA's member manufacturers produce more than 90% of the world's fragrances, its rules effectively function as law for nearly all companies. Chemists who have worked since around 2001 to make synthetic oakmoss 'knockoffs.' One of them, Cyrill Rolland, managed to imitate synthetically the way the scent of oakmoss seems to evolve, first evoking wet timber with a slightly bitter undertone of seaweed, and then changing to a dry, woody aroma. To untutored noses the fake products smell like the genuine oakmoss; however, there have been many complaints among more discerning consumers about the reformulated products. One prominent perfume writer even pronounced the art of fragrances "officially dead." Since perfumery is a $2 billion industry in which even a microliter substituion of one component for another can make the difference between a failure and megaseller, the limitation of oakmoss use has had a huge impact. As Guerlain's in-house perfumer Thierry Wasser explained, whenever some part is removed from an ingredient, "it leaves a hole."

Some perfumers, including Arcadi Boix Camps, have tried using patchouli, vetiver, or a synthetic 'mossy woods' note instead of oakmoss, with varying success. One example is Comme des Garcons White. Wasser's initial answer was to substitute with celery seed in the famous Guerlain chypre Mitsouko and their Parure, but subsequently he has developed a processed raw oakmoss material to mimic it without the specific molecule not allowed by the guidelines. Says perfumer Clement Gavarry, "Some ingredients are there just to wrap things up. They might add performance or make a fragrance last longer. But ingredients like oakmoss are there to provide character or give a crucial twist to the fragrance." One fragrance writer, Denyse Beaulieu, has called the reformulated fragrance type an 'iFrag,' a pun on IFRA and fragrance and a reference to the iPod, whose music she describes as "skinny and fleshless," with a seemingly accurate surface but an empty inner substance. She complains, "People want a sound bite of a fragrance — something nice, clean, and fresh" that avoids taking risks. William Troy, IFRA North America's president from 2007 to 2010, acknowledges that some essential components are sacrificed. "And you know what? We can't do otherwise," he says. "If we can't demonstrate a safe use level, it's not in our best interest to allow that material to continue to be used in a product, because there are going to be problems — image problems as well as adverse consumer reactions." Some people have suggested allowing higher concentrations of mosses provided there is a prominent printed warning on the box, while others have presented a 'quenching' hypothesis, in which the anti-inflammatory azulene, which occurs natuarlly in chamomile, would be added. However, aluzene has its own odor profile and a blue color that complicate this idea.

Recently there has been a more promising commercial answer to providing oakmoss scent: through the processes of gas chromatography-mass spectrometry analysis and fractionation – identifying and separating the different components of an individual ingredient by gradients during a phase transition, and removing the potential sensitizers – it's possible to get a substance that can be tweaked at the molecular level so that it is much closer to original whole oakmoss in its scent qualities. The company Mane, manufacturer of an increasingly popular oakmoss facsimile, claims that its natural substitute, derived from analysis of the oakmoss absolute and with a molecular structure kept as a closely guarded secet, is nearly identical in scent to oakmoss while still able to pass the IFRA tests.

Tree Moss

Pseudevernia furfuracea, commonly known as tree moss, is a lichen (or lichenized moss) that grows on the bark of 'nutrient poor' trees such as birch, pine, and spruce. This species, often somewhat carelessly included under the same common name as its botanic cousin oakmoss but growing less widely, has had numerous commercial roles, including use in perfume, Egyptian embalming, and medicine. Another species, Usnea barbata, also is used quite often in perfumery.
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Large amounts of tree moss (sometimes called fir moss), like true oakmoss, are processed in Grasse, France for the perfume industry. Its fragrance is said to be generally one-dimensional, more astringent and less complex or nuanced, and less like a 'wet forest floor,' than oakmoss. This results in a relative lack of 'fullness,' for which some perfumers try to compensate by adding other ingredients such as patchouli. Tree moss has a turpentine smell before processing. In perfumes, oakmoss softens the tartness of citruses/aledhydes with which is is mixed, providing a powdery effect (especially in conjuction with orris root), which tree moss does not give. However, tree moss can add a desirable, persistent, dry background dimension that works well in contrasting moister and richer qualities such as those of rose and tobacco absolutes. In terms of fragrance classification, tree moss may be considered to have a position somewhere between leather and oakmoss. In perfumes it also works as a fixative basically the same way as oakmoss.

Benzene extraction, which has been banned for decades from manufacturing of perfumes, produced very high-quality lichen extracts, and attempts to use other similar solvents have been only partially successful. Currently either pure hexane or mixtures of hexane with acetates (or more rarely isopropanol) are used to removed the crude resinoids from tree mosses. The resinoids are then treated further with ethanol to produce absolutes. Traditionally these processes have been performed after desiccation of the lichen, since fragrance has been thought to develop significantly during storage. The qualitative scent composition of tree moss or lichen extracts can vary widely, depending on the exact method of preparation and on the presence of any residual or environmental contaminants.

Soluble extracts from P. furfuracea var. furfuracea and var. ceratea, as well as specific individual compounds found in them, have antimicrobial activity against a variety of microorganisms. In areas of Andalucia (Spain), P. furfuracea still is used for treating infections, especially respiratory complaints. The thallus is washed and boiled for a long time to prepare a decoction which is drunk for this purpose.

Water extracts of this species have been shown to have a potent protective effect on genotoxicity caused by bismuth compounds such as colloidal bismuth subcitrate, and it has been investigated for its ability to absorb toxic heavy metals from solution. The metal-binding biosorption for copper and nickel suggests it may have potential as a biosorbent for medical treatment of heavy metal toxicity. Because P. furfuracea tends to bioaccumulate heavy metals proportional to their concentration in airborne particulates, it can be used as a monitor of air quality, although it has been noted that element accumulation is partly dependent on the hydration level of the specimen. Also, the species is sensitive to ozone concentrations, and ozone fumigation results in impairment of its metal absorption, so it can reflect ambient ozone levels. P. furfuracea has also been used to monitor the levels of radionuclides, such as those of Cesium-137 in Austria after the Chernobyl nuclear accident.

In ancient Egyptian embalming, P. furfuracea was packed into the body cavity of mummies, although it is not certain whether this was done because of the supposed preservative properties or because of its aromatic properties.

Other Lichens

Other mosses and lichens have been used for centuries in folk medicine, including for treatment of mouth ulcers, cough, diarrhea, rabies, baldness, bleeding, fungal infections, and epilepsy, and they still are used commercially as natural deodorants.

They also have been used for dying cloth, candles, and other products. In medieval Europe, lichen dyes were dissolved in human urine, and clothing yarns were immersed in the mixture to color them, with ammonium salts in the urine acting as a mordant to make the dyes permanent. Northwest Pacific native American cultures used a lichen that grows on the bark of pines and firs to make a canary-yellow dye for porcupine quills that were woven into baskets, and Bryoria lichen was used by other Amerindians to give a brown or green color to shirts and leggings. A brown dye from the lichen Permelia omphalodes is still used in modern hand-woven Harris tweeds from the Outer Hebrides.
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Certain toxic mosses have been used by Norwegians with baits to kill predatory wolves and protect their herd animal flocks, while digestible ones have provided flavoring for breads, beers (in place of hops), and salads, especially during times of famine.

'Oakmoss' as a perfume fragrance component is prominent in:

Abercrombie & Fitch 1892 Cobalt, Summer
Agua de Cheiro Saver Royal
Al Battash Concepts Ghala Zayed
Avon Wilderness, Windjammer
Azzaro Chrome Intense
Bloke Michael
Creed Aventus
Criminal Elements Ruben
Cuba Paris Green
Cuir de Russies (various)
Domenico Caraceni pour Homme
EastWest Bottlers Bluegrass
Faberlic Mon Roi
Frau Tonis Parfum No. 65 Eau de Berlin
Guerlain Mitsouko
Houbigant Fougère Royale
Jean Desses Gymkana
Jivago Red Gold
Joaquin Cortes Yekipe Pura Pasion
Juvena Lonestar
L'Artisan Parfumeur Riviera Palace
Le Prince Jardinier Arboretum
Loewe Esencia pour Homme
Luciano Soprani Uomo
LR/Racine Agent XY
Outremer Mousse de Chene-Oakmoss
Parfum Regence Oakmoss
Paris Elysees Dollar
Penhaligon Eucris
Pinaud Clubman
Pino Silvestre Muschi de Bosco
Ralph Lauren Safari
Scorpio Vertigo
Shirley May Don Carlos
Soyuzparfumerprom Diplomat
Thera Cosmeticos Zeus
Excellent again thank you John , I had seen oak moss in descriptions but never really knew what it was.
 
Mint/Menthol/Coolness

Citrus, green leaves, tart fruit, and lily of the valley are all described as cool scents, but most are not actually cooling. While a 'cool' perfume merely evokes pleasant associations, a truly 'cooling' one is instantly refreshing. The mint family is characterized by this invigorating 'cooling' effect. Menthol, the main component of mint essence or essential oil, provides the trigger for this through TRPM8 cold-sensitive skin receptors. The essential oil of all mint types is extracted from the plants through steam distillation. The oils are clear to pale yellow, with watery viscosity. The mint group includes Japanese mint, English mint, apple mint, curly mint, pennyroyal, peppermind, pineapple mint, spearmint, and water or bog mint, among others. The most important ones commercially are peppermint (M. piperita), spearmint (M. spicata), and wild/field/corn mint (M. arvensis).

In general, mint provides a fresh lift to all fragrance types, accenting the top note. It combines well with white flowers, especially with orange blossom and jasmine, which it also balances. It has become more important as a single note in some modern products that feature 'natural' market positioning. Until fairly recently it was rarely used much in perfumery, probably because of the fact that a fragrance with a bright minty note tends to evoke associations with toothpaste or other hygiene products. Other than Guerlain Aqua Allegoria Herba Fresca or Mentafollia and certain summer limited editions like Cologne Le Male Summer, the majority of experiments with a dominant mint note have just been in minor niche perfumery. Fragrances with the subgroup smell of mint cocktails can be allocated into separate collections: mojito, caipirinha etc. Such accords can be found in vintage Calvin Kline Crave, L'Artisan Parfumeur Batucada, Tom Ford Costa Azzurra, A Lab on Fire Eau d'Ipanema, Demeter Caipirinha, Pierre Guillaume Croisière Mojito Chypre, and Guerlain Homme. Mint essential oil or menthol also can be a part of fresh citrusy accords, such as Diptyque Oyedo.


Mint

Mint (also known as mentha, from the Greek 'míntha' for the nymph that Pluto turned into a sweet-smelling herb), with over 40 species and hybrids, is a genus in the family Lamiaceae. The Lamiaceae (or Labiatae) are also known as the deadnettle family or sage family. Many of them, including widely used culinary herbs like basil, rosemary, sage, savory, marjoram, oregano, hyssop, thyme, lavender, and perilla, are aromatic in almost all their parts. These flowering plants can be shrubs, trees (such as teak), or rarely vines. Besides those grown for their edible leaves, some are grown for decorative foliage, such as Coleus. Others are grown for seed, like chia, or for their edible tubers, such as various exotic potatoes and Chinese artichoke.
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The alternative family name Labiatae refers to the fact that the flowers typically have petals fused into an upper lip and a lower lip ('labia' in Latin). The flowers are bilaterally symmetrical with five united petals and five united sepals. They are usually bisexual and verticillastrate (a flower cluster that looks like a whorl of flowers, but actually consists of two crowded clusters). The leaves emerge oppositely, each pair at right angles to the previous one (decussate) or whorled. The stems are frequently square in cross section, but this is not found in all members of the family.

The family has traditionally been considered closely related to the Verbenaceae (verbena or vervain family), and in the 1990s, phylogenetic studies suggested that many genera classified in the Verbenaceae actually should be classified in the Lamiaceae or in other families of the order Lamiales.


Peppermint and Spearmint

Peppermint (Mentha × piperita, also known as Mentha balsamea wild.) is a hybrid mint, a cross between water mint and spearmint, with spearmint already being a hybrid itself. Peppermint is occasionally found in the wild with its parent species. While Western peppermint is derived from Mentha piperita, Chinese peppermint (or 'Bohe') comes from the fresh leaves of Mentha haplocalyx.
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Peppermint is indigenous to Europe and the Middle East, but it has been cultivated since the late 17th century and is mainly a cultivated species now. Cultivated plants have been selected for more and better oil content. Outside of its native range, areas where peppermint was formerly grown for essential oil often have an abundance of feral plants, and it is considered invasive in Australia, the Galápagos Islands, New Zealand, and the Great Lakes region of the U.S.

There are two main types of peppermint: black mint (also called English mint or mitcham mint) (rubescens nigra) and white mint (pallescens alba). Black mint provides most of the essential oil. The plant is generally harvested before it blooms, when it has the highest oil content, and/or during dry, sunny weather. It usually is harvested in the morning before the oil content is reduced by the sun.

The oil is obtained with steam distillation of the whole plant. The essential oil is nearly colorless. Usually, the shorter the distillation process, the higher the menthol content and the quality of the oil. Analysis of the chemical composition of the essential oil from peppermint (Mentha × piperita L.) demonstrates the main constituents to be menthol, menthone, and menthyl acetate, with the latter responsible for the minty aroma and flavor. The oil most often undergoes additional fractionating to remove unwanted components, such as the lightest fraction containing the unpleasant-smelling dimethyl sulfide. Japanese peppermint oil typically contains 85% menthol, while English oil has 60-70% and American oil 50-78%.

Black mint is cultivated in England, France, Germany, Argentina, Brazil, Romania, Hungary, Poland, Morocco, India, Ukraine, and many other locales. Peppermint is the most commonly used of the more than 25 species of the genus Mentha. In 2000-2006, world production was led by the United States, but more recently (2014) it has been claimed that Morocco and Argentina produce the largest harvests. In the United States, Oregon and Washington produce most of the country's commercial peppermint.
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White peppermint is less hardy and less productive. It is an evergreen perennial that is similar to the black type but is a lighter shade of green and lacks the red or purple flush that appears on leaves and stems of the black variety. White peppermint essential oil, more delicate in aroma, is quite rare.
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Peppermint was first described scientifically in 1753 by Carl Linnaeus from specimens that had been collected in England. He treated it as a species, but it is now universally agreed to be a hybrid. It is an herbaceous rhizomatous perennial plant that grows to be 30–90 cm tall, with smooth stems. The rhizomes are wide-spreading, fleshy, and bear fibrous roots. The leaves are downy and dark green with reddish veins, and they have an acute apex and coarsely toothed margins. The leaves and stems are usually slightly fuzzy. The flowers are white or purple, with a four-lobed corolla. They are produced in whorls around the stem, forming thick, blunt spikes. Flowering season lasts from mid- to late-summer. Peppermint is a fast-growing plant; once it sprouts, it spreads very quickly. Wild peppermint typically appears in moist habitats, including streamsides and drainage ditches. Being a hybrid, it is usually sterile, producing no seeds and reproducing only vegetatively, spreading by its runners.

In perfumery, peppermint oil interacts well with cedar, basil, bergamot, lime, marjoram, pine, rosemary, mandarin, and thyme. Very intense and more concentrated than most other steam-distilled essential oils, it is quite versatile as a middle note in fragrances, providing richness. At lower dilutions, it blends especially well with grapefruit and lemon top notes and lavender and eucalyptus middle notes.

In addition to its use in perfumery, peppermint has a variety of other applications. Fresh or dried peppermint leaves are often used alone in peppermint tea or with other herbs in teas (tisanes, infusions). Peppermint is used for flavouring ice cream, candy, fruit preserves, alcoholic beverages, chewing gum, and toothpaste, and as an odorant in some shampoos, soaps and skin care products.

Dried peppermint leaves have been found in Egyptian pyramids dating to 1000 BCE. Although it has been used in folk medicine for thousands of years for minor ailments (including topical use for muscle/nerve/joint pain or for itching), medicinal uses of peppermint have not yet been approved as effective or safe by the US Food and Drug Administration. With caution that the concentration of the peppermint constituent pulegone should not exceed 1% (140 mg), peppermint preparations are considered safe by the European Medicines Agency when used in topical formulations for adult subjects. Diluted peppermint essential oil is thought to be safe for oral intake so long as only a few drops are used. In this way, peppermint is commonly used as a digestive aid and for stomach complaints, headaches, respiratory symptoms, and nervous system disorders, and it is reputed to help concentration and focus. Although some have used peppermint oil for morning sickness, the oil has not been approved for use in pregnancy.

Although peppermint is commonly available as an herbal supplement, there are no established, consistent manufacturing standards for it, and some peppermint products may be contaminated with toxic metals or other substituted compounds. Skin rashes, irritation, or an allergic reaction may result from applying peppermint oil to the skin, and its use on the face or chest of young children may cause side effects if the oil menthol is inhaled. A common side effect from oral intake of high doses of peppermint oil is heartburn. Oral use of peppermint products may have adverse effects when used with iron supplements, cyclosporine, medicines for heart conditions or high blood pressure, or medicines to decrease stomach acid. The oil is undergoing preliminary research for its potential as a short-term treatment for irritable bowel syndrome. In high concentrations, ingested peppermint oil can cause abortions and should not be used by pregnant women.

Peppermint flowers provide nectar for organisms such as honeybees, but the plant's oil has a high concentration of natural pesticides, mainly pulegone and menthone, and is known to repel some pest insects such as mosquitos.

A less common peppermint chemotype is lemon mint or bergamot mint (Mentha citrata Ehrh). Its essential oil has a smell recalling lavender and bergamot, and it contains almost no menthol. This oil is rarely used in perfumery since it is much more expensive than bergamot and lavender oils.
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Another important species in the genus is spearmint (Mentha spicata, from the Latin 'bearing a spike,' or Mentha viridis), which is actually a hybrid of horse mint (Mentha longifolia or Mentha silvestris) and round-leaved mint (Mentha rotundifolia, itself a hybrid). Spearmint originated in Italy and France. Various types of spearmint are cultivated now in the U.S., Great Britain, Germany, and Japan. It is a perennial herbaceous plant, 30–100 cm tall, with variably hairless to hairy stems and foliage and a wide-spreading fleshy underground rhizome from which it grows. The leaves have a serrated margin, and the stem is square-shaped. Spearmint produces flowers in slender spikes, each flower pink or white in colour. Spearmint blooms in the summer (from July to September in the northern hemisphere).
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Mentha spicata was first described scientifically by Linnaeus in 1753. It is indigenous to the eastern Mediterranean, from Italy to Egypt. Mention of spearmint dates back to at least the 1st century AD, with description by the naturalist Pliny and references in the Bible. Ancient mythology also has descriptions of mint, including spearmint. It was introduced into England through the Romans by the 5th century, and early versions of toothpaste using mint in the 14th century suggest widespread domestication by that point. John Gerard's Herbal (1597) states that: "It is good against watering eyes and all manner of break outs on the head and sores. It is applied with salt to the biting of mad dogs," and "They lay it on the stinging of wasps and bees with good success." He also mentions that "the smell rejoice the heart of man, for which cause they used to strew it in chambers and places of recreation, pleasure and repose, where feasts and banquets are made." Spearmint is documented as being an important cash crop in Connecticut during the time of the American Revolution, at which time mint teas were popular because they were not taxed.

Chemically, spearmint essential oil is quite different from peppermint oil, with the major aromatic component being L-carvone, and menthol and menthone generally not exceeding 1%. L-carvone has a sweet minty smell, while its mirror enantiomer D-carvon (a main component of caraway essential oil) smells spicy and harsh. Spearmint oil also contains significant amounts of limonene, dihydrocarvone, 1,8-cineol, and carvyl acetate. Unlike oil of peppermint, oil of spearmint contains minimal amounts of menthol and menthone.

Unlike peppermint oil, spearmint oil has had few specific medical uses, but it has been used some in traditional medicines for minor ailments such as fevers and digestive disorders. It is widely used as a flavoring in toothpastes and chewing gums and to add aroma to shampoos and soaps. Spearmint leaves are infused in water to make spearmint tea, and it is an ingredient of the famous Moroccan Maghrebi mint tea. Spearmint is an ingredient in several mixed drinks, such as the mojito and mint julep. Sweet tea, iced and flavoured with spearmint leaves, is a summer tradition in the southern United States.

Spearmint essential oil has had some success as a larvicide against mosquitoes. Using spearmint as a larvicide is reputed to be a 'greener' alternative to synthetic insecticides due to the latter's toxicity and adverse environmental effects. Used as a fumigant, spearmint essential oil is an effective insecticide against adult moths.

Another common but less widely used mint species is corn mint (lat. Mentha arvensis L.), with several chemotypes whose essential oils mainly are used for menthol. A final plant classically similar to mint is geranium, due to the presence of menthone. Mint and geranium can be found combined in Frédéric Malle Géranium pour Monsieur, a scent said to be inspired by traditional fragrant Moroccan soap.


Menthol Crystals or Flakes

Menthol (a terpene alcohol, commonly called mint camphor or peppermint camphor) is an organic compound made synthetically or obtained from the oils of mints. It is a waxy, crystalline substance, clear or white in color, solid at room temperature and melting slightly above that. Naturally occurring menthol (l-menthol) is the l-rotatory enantiomer, while synthetic menthol is racemic, consisting of equal amounts of both enantiomers.

Peppermint and wild mint (Mentha arvensis), primarily grown in the Uttar Pradesh region of India, are the primary species of mint used to make natural menthol crystals and flakes. The crystals are obtained by freezing and then filtering the essential oil. Menthol flakes are crystals reduced to a powder. India and China are the largest producers of the world's natural menthol.
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It is said to have been known to the Japanese for more than 2000 years. In the West, menthol was first isolated chemically in 1771 by Hieronymus David Gaubius. It was named in 1861 by F.L. Alphons Oppenheim.

Stimulating the cold-sensitive TRPM8 receptors in the skin and mucosa, menthol causes the cooling sensation when it is inhaled, eaten, or applied topically (similar to the heat-sensor effect of capsaicin, the chemical responsible for the spiciness of chili peppers). It has a characteristic 'cold' smell, transparent and clean, with camphoric, green, and spicy tones. The corresponding ketone, menthone, has a minty smell with much brighter, herbal-green, anisic effects. In perfumery, menthol primarily is used to prepare menthyl esters, which emphasizer floral notes (especially rose) in fragrances. In perfumes and cosmetics, it has some disadvantages: it is quite volatile; has a verybright smell that is difficut to fit into aromatic compositions; has a bitter taste; and in higher concentrations, provokes a sensation of burning. Chemical investigations of menthol and similar 'cooling' materials have been conducted for almost a century, and about 1200 new entities have been synthesized, some more cooling than menthol, less volatile, and not bitter tasting. But few of them have been used yet in perfumery.

Menthol is included in many consumer products, including:
-nonprescription lip balms, cough medicines, and relievers of sore throat and minor mouth or throat irritation
-antipruritics
-topical analgesics, sometimes combined with camphor, eucalyptus oil, or capsaicin
-patches to reduce children's fevers
-transdermal drugs (as a penetration enhancer)
-decongestants for chest and sinuses (cream, patch, or nasal inhaler)
-sunburn medications (often associated with aloe)
-first aid products such as 'mineral ice' to produce a cooling effect as a substitute for ice in the absence of water
-aftershave products
-some cigarettes, for flavor and to reduce mucosal irritation (and also increasing nicotine addictive potential)
-oral hygiene products and bad breath remedies
-chewing gum and candy
-beauty products such as hair conditioners

Menthol's analgesic and counterirritant properties are mediated through selective weak activation of dermal agonist kappa-opioid receptors and blockage of voltage-sensitive sodium channels, which reduces neural activity. Studies show that it acts as a GABA receptor-positive modulator. Its anesthetic properties are similar to those of propofol. In 2017 it was the 193rd most commonly prescribed medication in the U.S., with more than 2 million prescriptions. It has been used in upper gastrointestinal endoscopy as an antispasmodic and smooth muscle relaxant. Menthol is used in dental care as a topical antibacterial agent, effective against several types of streptococci and lactobacilli.

It is used as a pesticide against tracheal mites of honey bees.

Most mint fragrances are deemed unisex, but some are somewhat sharper and aimed more toward men.

'Masculine' Fragrances with Mint or Menthol:

Abercrombie & Fitch 1892 Yellow
Al-Rehab Romantic
Altika Yves Rocher
Alt-Innsbruck Eau de Cologne
Amouage Beach Hut Man
Annick Goutal Eau de Monsieur
Aramis Surface
Armani Code Sport Giorgio
Avon Prime, Real, Musk Marine
Axe Shock, Black Chill
Azzaro pour Homme Wild Mint, Aqua
Barbasol Brisk, Pacific Rush
Battistoni Marte Red Planet, Marte 61
Calvin Klein Crave
Cartier Roadster
Chanel Bleu, Allure Homme Sport Eau Extreme
Creed Royal Mayfair
Davidoff Cool Water (various)
Durance en Provence Fresh Mint
Dzintars Hit Yellow, Lucky No.15
Emper Bandit
Frédéric Malle Géranium pour Monsieur
George F. Trumper Paisley
Givenchy Gentlemen Only Parisian Break
Guerlain Homme (various)
Hugo Boss Mats Hummels, Orange Made for Summer, Iced, Just Different
Humiecki & Graef Eau Radieuse
Issey Miyake Sport Mint
Jean Paul Gaultier Le Male (various)
Jequiti Champs Fort, Merci, l'Attitude Musique
Judith Williams Man No.2
Kanebo Goce
Korres Aktis
Liz Claiborne Curve Wave
l'Occitane Verdon
Marco Serussi White
Massimo Dutti Island Accord
Master Perfumer Grey Fougere No.9
Mennen Skin Bracer
Milton Lloyd America Sport, Colour Me Blue
Montblanc Legend Special Edition 2014
Mugler Kryptomint, A*Men (various)
Nautica Voyage Heritage, Midnight Voyage
Nickel Ulla Lala
Oriflame Glacier Fire, Eclat Toujours, Free Motion, Venture
Paco Rabanne One Million, Ultraviolet
Phaedon Oriental Mint
Pierre Cardin Signe
Prada Luna Rossa
Proraso Green
Ralph Lauren Big Pony No.3
Ricardo Ramos ZirYab Peppermint
Shirley May Sapphire Man
Versace Eros
Williams Aqua Velva Menthol Mist
Xerjoff Renaissance
Yves Rocher Altika, Eryo Blue, Bois de Cedre et Citron, Comme Une Evidence Green
Yves St. Laurent Live Jazz
Zara Man Silver Winter, 2012
 
Oriental Fragrances

Oriental fragrances comprise one of the major perfume categories on the typical fragrance wheel. They are distinguished by the use of warm, rich, exotic, and sweet notes. Overall tones can be herbal, spicy, dry, powdery, and/or resinous. The perfumes generally are opulent, voluptuous, and seductive. The meaning of the term 'Oriental' has changed over the last several decades, especially with the growing influence of Arabian perfumery.

This perfume genre is called Oriental because it represents the Western fantasy of the mysterious and sensual East that arose in the 19th century. At that time French artists such as Eugene Delacroix and Jean Ingres captured this dream in their paintings of lounging odalisques, tiger hunts, and harem scenes, and French perfumers translated these stereotypical visions through rich notes of vanilla, amber, patchouli, sandalwood, and musk. Although embodying a fantasy image, the Orientals were rooted in perfume's history, using many of the same ingredients that were initially used in India and Arabia at the beginning of fragrance creation. The first contemporary Oriental fragrances were Guerlain Jicky (1889), and Coty L'Origan (1905), Ambre Antique (1910), and Emeraude (1921).

Classical Oriental fragrances have used natural ingredients like heliotrope, sandalwood, coumarin, orris, myrrh, anise, vanilla, musk, and gum resins, but the combinations have been tweaked to aim them to men or women or as 'shared' scents, and they have evolved over time with the changing needs of perfume users. Typically they have strong sillage and are quite long lasting, due to heavy use of the base notes. They are generally extracted and mixed in an oil base that makes the perfume stick well to the skin and allows it to evaporate slowly over a long time. Their prevailing character often is 'adult' and most suited to evening wear.

The most popular Oriental notes in modern products are:
bergamot (top)
pink peppercorn (top-middle)
rose, nutmeg, jasmine, tuberose, ginger (middle)
tonka bean, amber, cedarwood, vanilla, sandalwood, patchouli, orris (base)
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Well-known classical Oriental fragrances are Guerlain Shalimar and Habit Rouge; Calvin Klein Obsession; Frederic Malle Musc Ravageur; Cartier Must; and Annick Goutal Ambre Fetich and l'Artisan l'Eau d'Ambre.

There are defined and recognized Oriental subfamilies, the major ones being Floral Oriental (Floriental), Soft Oriental, and Woody Oriental, which generally represent transition areas blending into adjacent ones on the standard fragrance wheels, along with Fougere Oriental, which combines aspects of all the subfamilies. More recently described subgroups include Spicy Oriental and the minor Aromatic Oriental (usually considered a part of the Floral Oriental type), Vanilla Oriental, and Fresh Oriental (also often combined into the Floral Oriental group). Those Oriental fragrances with dominant amber are usually considered in a separate group due to their accentuated warmth and sensuality.

Obviously some fragrances will lend themselves to more than one subfamily, and there can be disagreement among perceptions. Thus some of the perfumes listed in the groups below appear more than once.

Floral Oriental

Bordering on the Floral category on the wheel, these typically have a sweet, warm, dark, powdery base, often harmonizing with flowers such as gardenia, tuberose, rose, jasmine, peony, magnolia, lily of the valley, or carnation. They have the softness of florals and the warmth of true Orientals. The majority of them are primarily considered feminine or unisex. Aromatic florals, one of the oldest groups historically, are considered part of this category.

Some of the recognized more masculine Floral Orientals include:

Abercrombie & Fitch Oud Amour
Acqua di Parma Colonia Vaniglia
Amouage Molook
Bvlgari Man in Black, Garanat, Opalon
Cartier Declaration Essence
Elysees Conviction Black
Fragrance Kitchen Man from Ipanema
Gritti 19-68
Hugo Boss Bottled Oud Aromatic
Korres l'Eau de Parfum 20
Oriflame Excite Force
Phebo Patchouli
Rasasi Junoon Satin
Roberto Cavalli
Sapientiae Niche Ofanins
Xerjoff Shooting Stars Modoc
Zara Gold Edition

Soft Oriental (Incense)

The base notes of these perfumes are not as sweet or heavy as those of classical Orientals, and they are less balsamic and animalic. Their blends of flowers, spices, and amber create a softer but still sensual style. Incense frequently is added for a darker and warmer composition.

Typical masculine Soft Orientals are:

Acqua di Parma Colonia Mirra
Cacharel Loulou
Diptyque l'Eau
Estee Lauder Youth Dew
Jean Patou Sublime
Kenzo Jungle l'Elephant
Chanel Coco
Serge Lutens Ambre Sultan
Robert Graham Valour

Woody Oriental

These have prominent wood notes that temper the sweetness of the vanilla, tonka bean, amber, and balsamics. Their accents provide what has been described as a 'luminous' effect, and they are sometimes considered 'artistic.' They often contain warm sandalwood and rosewood and dry notes of cedarwood, patchouli, agarwood, or vetiver. These are the most popular Oriental fragrances for men. Aromatic woods are generally included in this category.

Masculine Woody Orientals include:

Acqua di Parma Colonia Mirra, Colonia Oud
Alexandria Alexander the Great, Aromatic Conflict, Himalaya Mountains, Extreme
Alfred Dunhill Desire, Pursuit
Amouage Epic, Beloved, Figment, Interlude Black Iris, Interlude, Overture
Annick Goutal Sables
Ariana & Evans Khalifa
Axe Provocation
Azzaro Duo
Burberry Brit, London
Bvlgari Ambero, Notte, Man, Man Black Orient, Silver LE, Falkar, Gyan, Omnio
C.O. Bigelow Barber Cologne Elixir Black
Cacharel Nemo
Calvin Klein Contradiction, Dark Obsession, Encounter, Euphoria (various), Obsessed, Obsession
Carolina Herrera 212 (various), Insignia
Cartier Declaration, l'Envol de Cartier, Must Cartier, Santos
Cerruti 1881 Black
Chanel Allure (various), Bois des Iles, Egoiste
Chopard pour Homme
Christian Dior Faahrenheit 32, CC Patchouli Imperial, Dune
Crabtree & Evelyn Sandalwood
Creed Bois du Portugal, Himalaya, Santal Imperial
Davidoff Horizon Extreme, Silver Shadow, Brilliant Game, Game Intense, Zino
Dolce & Gabbana By, One Royal Night, Velvet Incenso
Donna Karan Chaos
Dzintars My Version (various), Ridzinieks, Strong Man
Emanuel Ungaro for Him
Ermenegildo Zegna Amber Gold, Indonesian Oud, Roman Wood, Zegna New York
Fendi Theorema Uomo
Floris Patchouli
Fragonard Eau de Hongrie, Zizanie
Geoffrey Beene Grey Flannel
Giorgio Armani Code (various)
Givenchy Gentlemen Only Intense, Pi (various), Very Irresistible
Gucci Envy, Guilty Absolute
Guerlain Habit (various), l'Homme Ideal (various), Samsara
Halston Man Amber
Hugo Boss Bottled Oud, Scent Private Accord
Hermes Eau de Merveilles, Terre d'Hermes
Issey Miyake l'Eau d'Issey Or Encens, Nuit d'Issey Polaris
Jean Paul Gaultier Le Male
Jequiti Malte, Portiolli, Stame, Thiaguinho, Uzon
John Varvatos for Men, Dark Rebel, Oud
Joop! Homme Black King, Homme
Jovan Ginseng NRG
Karl Lagerfeld Classic
Korres Black Pepper Cashmere Lemonwood, Saffron Tobacco
L'Occitane en Provence Eau des Baux
Masaki Maatsushima Aqua Mat Homme, Art Homme
Michael Kors for Men, Extreme Night
Molinard Habanita
Montale Red Vetiver
Mugler A*Men (various), Alien Man, Taste of Fragrance
Nikos for Men
Oleg Cassini for Men
Oriflame Dark Wood, Eternal Man
Paco Rabanne 1 Million, Black XS (various), Ultraviolet
Pecksniff's Cardinal, Tompion
Penhaligon's Hammam Bouquet
Pierre Cardin Centaure Cuir Casaque, Collection Cedre-Ambre, Revelation Energy
Prada Luna Rossa Black, l'Homme Absolu, l'Homme Intense
Ralph Lauren Polo (various)
Remy Latour Cigar Black Oud, Cigar Mystic Scent, Manes
Roger & Gallet l'Homme Vetyver
Royal Copenhagen 1775 Noble, 1775 Valor, 1775 Rival
Santa Maria Novella Opoponax
Tom Ford Noir Extreme
Versace pour Homme, Oud Noir, Versus Uomo
Viktor & Rolf Antidote
Yardley 442 Active
Yves Rocher Ambre Noir, Hoggar
Yves St. Laurent l'Homme Intense, Collection M7, La Nuitde l'Homme, Opium Eau d'Orient
Zara (various)

Fougere Oriental

This represents the blending of nearly all the major Oriental components (warm, woody, spicy, and sweet accords) along with refreshing aromatic notes of lavender, rosemary, coumarin, and oakmoss. This group is especially popular with men.

Men's Fougere Oriental perfumes:

Alexandria Ete Sauvage, Greek Horse, Mr. Sillage, Royalty
Alfred Dunhill Desire Black, London
Amouage Jubilation XXV Man
Axe Africa, Anarchy for Him, Dark Temptation, Musk, Phoenix, Signature Rogue
Azzaro Amber Fever, Elixir Bois Precieux, Naughty Leather, Solarissimo Favignana
Burberry Element
Bvlgari Kobraa
Calvin Klein Eternity Flame, Eternity Now, Euphoria Gold
Carolina Herrra 212 (various)
Caron Impact pour un Homme
Cartier Pasha
Cerruti Si
Chanel pour Monsieur
Chopard Heaven
Christian Dior Sauvage
Claus Porto Musgo Real Agua de Colonia No. 1 Orange Amber
Crabtree & Evelyn Moroccan Myrrh
Dana Canoe
Dzintars Lucky No. 10
Emanuel Ungaro Apparition Homme Intense, Ungaro
Fila for Men
Fiorucci Extreme Sport
Giorgio Armani Attitude, Eau de Nuit, Stronger with You Intensely
Givenchy Play Intense, Xeryus Rouge
Gritti Decimo
Hermes Equipage
Hugo Boss In Motion
Jean Patou
Jean Paul Gautier Le Male (various), Ultra Male
Jequiti l'Attitude Musique, Prive Homme Fortune, So Voce Fabio Jr. Momentos
Jo Malone Amber & Lavender
Johan Varvatos JVxNJ Crimson
Joop! Homme (various)
Kenneth Cole Mankind Hero
Lacoste Elegance
L'Acqua di Fiori 310, U.Man
Lancome Hypnose
Montale Sliver Aoud
Mugler A*Men (various)
Nikos Sculpture
Oleg Cassini
Oriflame Full Moon, Possess Man
Penhaligon's Agarbathi
Pierre Cardin Bleu Marine
Pino Silvestre Deep Charisma
Rasasi Al Wisam Day
Rochas l'Homme, Monsieur Rochas
Salvatore Ferragamo Acqua Essenziale Blu
Swank Jade East
Thera Cosmeticos (various)
Versace Dreamer
Yves St. Laurent Jazz Prestige, La Nuit, La Nuit Eau Electrique
Zara (various)

Spicy Oriental

The term Oriental applies especially well to this group, since they often have multiple strong, balanced ingredients rather than a specific or signature accord. Hot, sensual, and with a typical zesty and adventuresome spirit, they are a favorite with both genders, especially in the cold winter season. Popular notes include cinnamon, clove, pink pepper, mace, thyme, and nutmeg, and common floral additions are mandarin, bergamot, and orchid, which give the perfume an added Eastern flavor. Amber sometimes is added for more warmth. Men seem to prefer Spicy Orientals that also mix vanilla and resins. This group is has remained popular and less changed than some of the others.

Popular men's products:

Acqua di Parma Colonia Quercia
Alexandria La Dolce Vita, Ovation
Alfred Dunhill Moroccan Amber
Amouage Lyric, Fate
Aramis Classic Reserve, Havana, JHL
Azzaro Decibel
Boucheron Homme Fraicheur 2008, Jaipur
Burberry Brit New Year, London
Bvlgari Man in Black Essence, Le Gemme Yasep
C.O. Bigelow Barber Cologne Elixir, Bay Rum
Calvin Klein Heat, One Shock, Eternity, Obsessed
Carolina Herrera Bad Boy, CH Men, CH Men Grand Tour
Cartier Must, Santos Concentree
Cerruti 1881 Signature
Chanel pour Monsieur Concentree
Christian Dior Fahrenheit, Sauvage
Claus Porto Real Black Edition
Dana English Leather Spiced
Davidoff Hot Water, Hot Water Night
Dolce & Gabbana ll La Force, The One Collector, One Mysterious Night
Emanuel Ungaro pour l'Homme II, Power, U Fever
Ermenegildo Zegna (various)
Floris Palm Springs for Spencer Hart
Fragonard Desert
Giorgio Armani Code (various), Attitude Extreme, Gio 2015
Givenchy Gentlemen Only Absolute
Gucci Made to Measure
Hugo Boss Soul, Scent Absolute, Dark Blue, Red
Jequiti Champs Velocite
Jovan Satisfaction
Karl Lagerfeld Homme, KL, Photo
Korres Saffron Amber Agarwood Cardamom
L'Occitane en Provence Au Bresil - Cumaru
Lacoste Timeless
Maurer & Wirtz Tabac Fire Power
Narciso Rodriguez Intense
Nikos Sculpture Homme God's Night
Oriflame Be the Wild Legend, ID Player, Intense Embrace Him, Manful, Signature Heritage, Voyager
Paco Rabanne Pure XS Night
Panama 1924 Sport, 2.0
Paul Sebastian Silver, Kinetic
Pecksniff's Charismatic
Penhaligon's Endymion, LP No. 9, Uncompromising Sohan
Pierre Cardin Revelation
Rasasi Daarej, Tasmeem
Roja Enigma, Madison
Royal Copenhagen 1775 Rival, Noble
Shulton Old Spice Original
Viktor & Rolf Spicebomb Extreme
Xerjoff Coffee Break Golden Dallah, Shooting Stars Kobe
Yardley Bond Street, Cougar
Yves St. Laurent Body Kouros, Opium (various)
Zara (various)

(Vanilla Oriental)

With warm gourmand characters, this group blends already sweet perfumes built on Oriental notes (the usual woods, flowers, spices, and resins) with other sweet components, such as caramel, vanilla, chocolate, almond, honey, and burnt sugar. Products of this type is especially popular among women, but several of them are aimed at men:

Axe Provoke
Carolina Herrera 212 VIP
Ermenegildo Zegna Strength
Frederic Malle Monsieur
Giorgio Armani Night
Guerlain l'Initial
Inessance Terre d'Evasion
Jacques Battini De l'Ambre Shady
Jean Paul Gaultier Kokorico by Night
John Varvatos Rock Volume 1
Joop! Wow!
Mugler A*Men Pure Havane, Angel Glamorama
Oriflame S8 Night
Remy Latour Cigar Vanilla Tonka
Ralph Lauren Ralph Hot
Ted Lapidus Intenso
Thera Cosmeticos Amatus
Yves St. Laurent Black Opium Storm Illusion

(Fresh Oriental)

Often considered a part of the Floral Oriental family, this newer group has a lighter interpretation, with citrus oils included to brighten and lift the aroma, making them more applicable to daytime use while still having an underlying exotic beauty. Examples include:

10 Corso Como Uomo
Acqua di Parma Colonia Mirra
Baldessarini Black
Bvlgari Le Gemme Garanat, Man Black
Davidoff Cool Water Intense
Kenzo Aqua Kenzo Neo
Lacoste Timeless
Paco Rabanne 1 Million, Invictus Legend, Pure XS
Prada Luna Rossa Sport
Rasasi La Yuqawam Ambergris Showers, Relation, Truly, Xtraordinaire Musky
Roja Madison
Royal Copenhagen 1775 Valor
Zara Amber, Blue Spirit, CC Sydney, Denim Couture Red, Weekend Hoodie, Tobacco Intense Dark

(Aromatic Oriental)

This is generally deemed a part of the Floral Oriental collection but is thought to be significantly separate by a few. The fragrances typically possess a very intensive grassy-spicy tone provided by sage, rosemary, cumin, lavender, and other plants, which often is combined with uplifting citrus notes. They seem to be especially popular with men. Included in this group are:

Abercrombie & Fitch First Instinct
Bvlgari Le Gemme Opalon, Man Black Orient
Chanel Allure Sport
Chopard 1000 Miglia Chrono
Giorgio Armani Code A-List
Hugo Boss The Scent
Jean Paul Gaultier Le Male, Le Male Aviator
Karl Lagerfled Bois de Cedre
Lacoste Land
Mugler Alien Man
Panama 1924 Espresso Napoletano
Rasasi Power Plus
Roja Risque
Taylor of Old Bond Street Platinum
Xerjoff Coffee Break Golden Moka
Zara C4shmer4n, For Him


Oriental Perfume Name/Concept Controversy

Many experts consider the term 'Oriental' to be misleading and vague or worse. Although there are old and sophisticated fragrance traditions in North Africa, the Middle East, and the Far East, the typical modern perfume of this type has little in common with their classical forms. Amouage Gold, a well-known modern fragrance from the company founded by the Omani royal family, does exploit and typify the cliché, with a signature powdery-mossy accord built around Omani rose and frankincense. But the Oriental family of French perfumery initially grew as part of the stereotypical orientalist Western arts movement of the 19th and early 20th centuries, and like the widely varying philosophies of the artists of that time, the word came to mean many things, often seemingly conflicting. This confusing state has been worsened by the necessity of many of the fragrances being constantly reformulated to keep them in compliance with various governmental regulations.

'Oriental' possibly was used at first to describe perfumes actually made with ingredients from or associated with the Orient, especially the Middle East, and subsequently ingredients that approximated or suggested those 'warm' scents. The first product to use the term in print was Guerlain Shalimar, launched in 1925 in Paris at the International Exhibition of Decorative Arts and described as Oriental "because its suave gourmand notes recall the sweet balsams of the lands of the One Thousand and One Nights." It was said to have been inspired by a maharaja visiting Paris who told Jacques and Raymond Guerlain the story of the gardens of Shalimar, which sheltered the Mughal emperor Shah Jahan and his Persian wife Mumtaz Mahal, for whom he built the Taj Mahal.

Outside the perfume world, 'Oriental' is a word not only reflecting Western fantasies, but also suggesting 19th century and early 20th century European colonialism. In his book Orientalism, Edward Said described it as "a sign of European-Atlantic power of the Orient" and an artificially constructed understanding of what Westerners believed the Orient to be: an exotic, mysterious, and culturally opposite place from the West. The word was used to simultaneously fetishize and degrade Eastern cultures thought to be less sophisticated or 'advanced' than Western ones, and it painted a culturally homogenous image of a vast group of people whose only true similarity was that they were non-European. More recently, it has become clear that when the term is applied to people, it is seen as politically incorrect and insensitive. In 2016 President Obama signed a bill eliminating all uses of the term Oriental from federal law. Grace Meng, a member of Congress from New York who sponsored the bill, called the term "outdated" and "offensive." She said, "Many Americans may not be aware that the word 'Oriental' is derogatory. But it is an insulting term that needed to be removed from the books."

So is the use of the term Oriental a problem in perfumery? Dr. Amy Hanser, Associate Professor of Sociology at the University of British Columbia, says in somewhat typical sociological language, "It points to the ways in which we are sensitive to (negatively) racializing language when applied to people, but we might fail to recognize racializing discourse that is not directly applied to human bodies. But the idea of a perfume being an 'Oriental' fragrance might indeed be drawing upon stereotypes about a region (and its people) that make the term problematic when applied to people."

To some it seems bizarre that it still is being used to describe fragrances. Alexa Nishimoto, a freelance fashion designer with the Japanese American Museum in Los Angeles, says, "It feels like [brands] attempt to use one universal word to convey all Asian cultures, which is reductive to those who know that the nuances of each culture can be vastly different and don't fall under just one umbrella term." Dana El Masri, an independent perfumer, agrees: "[The term Oriental] is outdated and unnecessary. It also doesn't say much about the fragrance family and has become more of a reference to a 'spice' structure that was created in the 1920s than anything else. It is too broad a reference and perpetuates a typically Western/Occidental point of view."

But to traditional perfumers and perfume aficionados, it remains an 'official' classification. Says Marian Bendeth, a fragrance expert and perfumery owner, "It's where it originates, and it's a beautiful thing and certainly helps me because I deal with classifications all the time." She sees the term not as cultural but as geographical, denoting the origin of certain commonly-used fragrance notes.

The non-profit Institute for Art and Olfaction (IAO) refrains from using Oriental as a perfume classification, referring to it only if absolutely necessary as "the category most commonly known as Oriental, which needs renaming." One member of its board of directors, Julianne Lee, says, "I understand that the term is not one that is easy to sidestep for those in the fragrance community as so-called 'Oriental' perfumes are crucial to perfume history. However, I do find it lazy and harmful terminology." El Masri has suggested breaking down the single fragrance family into subfamilies based on geographical regions: "There are huge differences between a fragrance created in Malaysia by Malay people and a Japanese one, obviously, so why not classify it as such?" But many modern perfumes that have evolved from those created a century ago do not fit into geographical definitions at all, which has prompted some experts to propose coining terms such as 'ambery' that describe the actual olfactory notes, although there is wide disagreement about how this could be accomplished. Lee has noted that in terms of primary olfactory notes, so-called Oriental fragrances can generally be divided into two categories: those that incorporate an 'ambreine' accord (bergamot, vanilla, rose) and those that use a 'mellis' ('honey-sweet' or 'pleasant') accord (benzoin, eugenol, lily-of-the-valley, spices), but she also recognizes that many contemporary Oriental scents have branched out and mutated so much that they may not even warrant use of the Oriental label or accord labels at all. "Oftentimes, they are mere attempts at populating the 'Oriental' category, clearly visible from the marketing narrative and strategy."

So the controversy continues.
 
Sandalwood

Sandalwood is a classic fragrance. It has an Oriental woody-floral odor profile, creamy, smooth, soft, and sensual. As a single fragrance, sandalwood is sweet, green, and nutty in its top aspects and warm and rich in later phases. It blends well with almost all oils, and it pairs well with floral or other wood scents such as violet, rose, orange blossom, jasmine, ylang ylang, cypress, patchouli, and oakmoss. It frequently is combined with musk, amber, tea, cumin, and spices such as cinnamon, clary sage, coriander, fennel, pepper, and clove. It complements and balances frankincense and myrrh especially well. Like vetiver and amber, it is used primarily as a base note for perfumes in the Oriental, Woody, Fougère, and Chypre families. It lacks the sharpness of rosewood, cedarwood, and vetiver, and to some noses it is perceived as animalic. At higher concentrations, sandalwood can overpower other components of a composition, but at lower levels it adds softness, fullness, and roundness, as well as acting as a fixative for more volatile head note ingredients, enhancing their longevity.
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Initially during the Georgian era of perfumery (ca. 1714-1835), sandalwood was considered to be a masculine scent, but in 1796 the perfumer James Floris developed Staphanotis, a feminine fragrance that blended base notes of sandalwood and musk with orange blossom, staphanotis, and lily of the valley. Subsequently sandalwood has become much more popular in feminine perfumes, used in the base of almost half of them produced since that time.

The name comes from the Sanskrit chandanam (also meaning 'soothing') or sandanam in Tamil. Sandalwood is a medium-sized parasitic evergreen tree (getting nutrients from other trees in its early stages) with slender drooping branches and brown or red bark. The leaves are 3-4 cm long and elliptic, and the small unscented flowers are numerous and pale straw to brownish-purple. The tree produces fruit, and birds disperse its seeds. It grows relatively slowly and can live up to 100 years. The wood is hard and fine-grained, with the sapwood pale green or white and odorless and the heartwood yellowish-brown and strongly scented. The concentration of fragrant oil increases with the tree's age, and unlike many other aromatic woods, it retains its fragrance for decades if stored properly.
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Indian sandalwood (Santalum album, sometimes called 'East Indian sandalwood' since colonial times) is thought to be indigenous to southern India and East Timor and introduced to Nepal, Bangladesh, Sri Lanka, China, Australia, Hawaii, and other Pacific islands. It belongs to the family of woods that includes rosewood, cedar, and cinnamon tree. Other Santalum species are native to many other regions. The highest quality tree has been Mysore white sandalwood from southern India and Tamil Nadu, now reduced almost to extinction by overharvesting. At one time 70-90% of the world's sandalwood oil production was in India, but the majority now comes from Australia. All sandalwood trees in India, Pakistan, and Nepal now are government-owned, but despite some measures of government protection, illegal logging and trading continue on a large scale (partly due to law enforcement corruption), as does associated clandestine dilution, which makes the oil less desirable.
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Native Australian sandalwood (S. spicatum), a different species with a sharper, more resinous, and earthy but still quite pleasant odor, has replaced S. album for most perfumery. Production of Australian oil peaked in 2009 and has continued at significant levels. However, with increasing use of synthetic sandalwood substitutes in perfumery and personal care products, a growing proportion of Australia's natural oil production has been diverted to the chewing tobacco industry.
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Overall, there are at least 25 species in the genus Santalum. New Caledonian sandalwood (S. austrocaledonicum), growing on that archipelago and on Vanuatu, produces a very high-quality oil that is quite similar to the Indian oil. Species grown in Hawaii also have been of high quality and were actively exploited in the late 18th and early 19th centuries until the tree supply finally dwindled. Others that have been used intermittently include red sandalwood, false sandalwood, camwood, and bastard sandalwood. Typically they lose their aroma more quickly than the Indian or Australian species. African sandalwood and the so-called 'American sandalwood' or sea torchwood have nothing in common botanically with S. album, and their oils are chemically quite different; but they are several times cheaper than Santalum species, and although their oils differ considerably in smell for most people, they are similar enough to have been used, sometimes surreptitiously, in products called 'sandalwood,' especially niche products.
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Sandalwood essential oil is most often obtained from the wood through steam distillation. It can also be extracted less efficiently through water distillation, solvent extraction, and vacuum co-distillation. Because it can regenerate from the stump, the tree was cut down for harvesting in the past, but now it more often is completely uprooted during the rainy season. Consequently the oil can be distilled from all the wood, including the trunk, branches, and roots, in order maximize profit. The wood is ground to powder and soaked in water for about 48 hours before distillation. The four-step steam-distillation process (boiling, steaming, condensation, and separation) takes 18-36 hours to complete, longer than nearly all other essential oils.
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In the past, only trees older than 40-80 years and at full maturity, with the highest concentration of fragrance in the heartwood, were used for oil, but today the average age of trees commercially harvested is 8-16 years (or a minimum of 15 years in Australia). The pale gold-brown, moderately viscous oil retains fragrance for a long time when stored. The source of the fragrance is santalol, in its alpha and beta isomers. Australian sandalwood oil contains 35-40% santalol, while Indian sandalwood has had 70-90%, with the superior Mysore type having a minimum of 90%. Eugenols provide a minor additional 'smoke-dried' aspect, and carbonyl compounds add flowery undertones. The overall sandalwood oil composition depends on the species, region grown, soil location, age of tree, and possibly the season of harvest and extraction process, and thus there can be significant variability.
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The S. album species population is now recognized as 'vulnerable,' and since 2004 Indian sandalwood has been listed on the IUCN Red List. Other than the oil produced by its own governmental growers, India has banned extraction of oil and export of sandalwood materials. Efforts are underway internationally to save the trees from extinction and regenerate S. album production. In addition to the subsidized government farming in the Indian state of Karnataka and Tamil Nadu, Indian sandalwood, including the Mysore type, now is grown on large plantations in western Australia alongside the indigenous Australian variety. With newer techniques of irrigation and fertilization, tree growth has been boosted so that a 15-year-old tree has the same oil levels as a 30-year-old tree did in the past. Australian producers in Kununurra are increasingly planting Indian trees, but whether establishment and growth of new plantations there can significantly restore the groves as a source of oil remains to be seen.

With decreasing stocks of Mysore and other Indian sandalwood, perfumers have had to reformulate their perfume products, some of which - especially the most renowned - were purported at one time to contain up to 40% natural sandalwood. Scientists have tried unsuccessfully for decades to develop protocols for the commercial synthesis of organic sandalwood oil, but efforts continue with new developments in biotechnology that raise hopes for the future. Companies also have been trying to find synthetic substitutes that imitate the chemical structure and scent of the natural oil. The first substitute molecule was discovered in Germany in 1947, with subsequent further evolution, including development of Santalidol in the Soviet Union. Santalidol, a mixture of several substances with similar structures, was mass produced commercially beginning in 1956. Since then, variations of it having somewhat differing ingredient ratios and smells have been marketed, with Sandalore and Bagdanol being the most common by the 1970s, as use of natural sandalwood oil began to decrease. The alternative probably best-known historically is Sandenol, whose chemical structure is most closely related to the santalol isomers and which was said to have an aroma quite similar to that of the natural oil. Among other widely used alternates are Javanol, Polysantol, Firsantol, Levosandol, Ebanol, Fleursandol, and HomoPolysantol. Javanol, Ebanol, Sandela, Santaliff, and Santalore have been claimed by their users to be the strongest and most true to natural sandalwood, but there is disagreement, and none can exactly match the complexity and richness of true sandalwood. Due to its unique technical properties (lasting power, strength, diffusivity, and ability to mix well with other compounds), Javanol from Givaudan has become the favorite among modern perfumers. A major advantage of synthetic oils over the natural form is that they provide consistency of composition and quality from batch to batch.

The documented use of sandalwood goes back about 4000 years to India, Egypt, Greece, and Rome. Ramayana, an Indian epic poem written in the 4th century BCE, first mentions the ancient burning of sandalwood slivers as incense. When sandalwood was abundant, especially in the 15th to 17th centuries, many temples and other structures were built with its timber, as were sculptures and furniture. In Egypt, it was an embalming ingredient and was believed to release the souls of the dead in reincarnation. It has been highly prized for wood carving, including creation of religious icons, rosaries, fans, sewing boxes, and toys, and this still is done using wood from trimmings and immature trees killed by disease. Sandalwood has been used in solid perfumes for centuries by Arab perfumers. In the 18th century it became a popular ingredient in European perfumes and cosmetics, and it also was used then to scent Spanish Córdoban leather.
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Sandalwood oil and wood have been a part of many different religious practices, including Hinduism, Sufism, Jainism, Buddhism, Zoroastrianism, Shamanism, and Taoism. The wood of the tree is powdered and made into a paste that is integral to many rituals and ceremonies, and it is used to decorate icons and altars. The paste and oil (applied to the forehead, neck, or chest) and the smoke from burning sandalwood incense have been thought to calm and focus the mind for meditation and prayer. Indian paintings show images of snakes curling around sandalwood trees, representing legends in which the tree is said to release such a beautiful scent that serpents are charmed by it.
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The essential oil is used in aromatherapy for its stress-reducing, calming, and soothing properties, and it is considered to be an aphrodisiac, especially in massage oil. It is a natural astringent, firming and toning the skin. It has been used for centuries in Chinese and Indian Ayurvedic medicine as an antiseptic, anti-inflammatory, antispasmodic, analgesic, diuretic, emollient, expectorant, hypotensive, and sedative. Sandalwood is claimed to be beneficial for rheumatism and gout, and it may have benefits for treating anxiety and depression and even cancers. Synthetic sandalwoods have been shown to stimulate skin OR2AT3 receptors, which may promote wound healing and scalp hair growth.

Aboriginal Australians eat sandalwood seed kernels, nuts, and fruit, and early European settlers there used the fruit in making jams, chutneys, and pies. Modern chefs have experimented with the nut as a substitute for macadamia, almond, and hazelnut, especially in Southeast Asian-style cuisine. The oil and some of the synthetic sandalwood analogues are used as a flavoring agent in candy, ice cream, baked goods, puddings, gelatin, and beverages. Due to its preservative and antiseptic properties, sandalwood often is included in soaps, other beauty products, candles, air fresheners, and industrial products. Finally, because of its low fluorescence and optimal refractive index, sandalwood oil has been used as an immersion oil for microscopy. There has not been extensive research conducted on the safety of sandalwood oil, but because there have not been any significant adverse effects documented in the scientific literature, it generally is considered quite safe and continues to be used commonly.

Many sandalwood perfume products have 'sandalwood,' 'sandalo,' or 'santal' in their names and can be identified easily. Other scents without those words in their names but with significant a sandalwood presence and usually designated as masculine include the following:

Aesop Marrakech Intense
Amouage Interlude, Epic, Memoir
Aramis Havana
Balenciaga Eau
Blanche Byredo Blanche
Burberry Mr. Burberry
By Killian Sacred Wood
Calvin Klein Liquid Gold Euphoria, Contradiction
Cartier Declaration d'un Soir
Caswell Massey Tricorn
Chanel Egoiste, Bleu
Christian Dior Leather Oud, Patchouli Imperial, Vetiver
Comme des Garcons Concrete, Wonderwood
Creed Himalaya, Bois du Portugal, Silver Mountain Water
D.R. Harris Marlborough
Davidoff Cool Water
Dior Fahrenheit
Diptyque Tam Dao
Dolce & Gabbana D&G
Donna Karan Chaos
Dunhill 51.3 N
Fabi per Lui
Fragonard Zizanie
Fulton & Roark Shackleford
Gucci Envy, Rush
Guerlain Habit Rouge, l'Eau Boisee, l'Instant, Heritage, Arsene Lupin Voyou
Guy Laroche Drakka Noir
Hermes Bel Ami
Histoire de Parfums 1725 Casanova
Jean Paul Gaultier Le Male
Jill Sander Man III
L'Acqua di Fiori Tennis
Laurent Mazzone Black Oud
Le Cherche Midi
Lush Smuggler's Soul
Maître Parfumeur et Gantier Grain de Plaisir
Maurer & Wirtz Marrakech Tale
Oscar de la Renta pour Lui
Pal Zileri Sartoriale
Penhaligon's Hammam Bouquet
Prada l'Homme
Profumum Roma Olibanum
Proraso Red
Revillon pour Homme
Rochas Macassar
Rosendo Mateu No. 1, No. 6
Scorpio Gold
Shaik Gold
Stetson Preferred Stock, Caliber
Tom Ford Exxtreme, Noir
Tom Frank Black 1
Valentino Noir Absolu
Van Heusen
Versace Black Jeans
Xerjoff Richwood
Yves St. Laurent Jazz
Zadig & Voltaire This is Him
Zara For Him 2018, No Night
 
Benzoin

Benzoin, commonly called storax, gum benzoin, or gum benjamin, is a balsamic oleoresin (a mixture of resin and essential oils) from the Styrax tree. Styrax (also called storax or snowbell) is a genus of around 130 species of shrubs or trees in the family Styracaceae and is native to temperate-tropical regions of the Northern Hemisphere. The majority of trees are in Eastern and Southeastern Asia (especially Sumatra, Java, and Thailand), but they also are found now in parts of southeastern North America and in South America, with a single species in the Mediterranean. The trees have deciduous or evergreen, alternate, ovate leaves and white flowers. The fruit is an oblong dry, smooth drupe (stone fruit).
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Benzoin resin is harvested like frankincense and myrrh once the trees are at least 7-10 years old. The hill tribe farmers climb to a height of 10 meters using rope ladders and make V-shaped incisions in the bark, and after several weeks the exudate forms tear-shaped lumps that look like caramel toffee. The tears are cleaned, sorted, and graded into quality groups. The first 3 years of a tree's life produce the best resin. Production continues for 10-12 years, after which the tree is cut down and the residual gum is scraped from the bark. Commonly used are the resins of the species S. tonkinensis, S. benzoin, and S. benzoides. Benzoin should not be confused with the balsam of the same name, which comes from the Hamamelidaceae family.
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Benzoin resin can be distilled, but most often it is solvent-extracted with alcohol from the resin. This produces are dark brown solid mass which is diluted with dipropylene glycol to varying ratios to give resinoids of differing viscosity. For perfumery it is further diluted in ethanol (to about 30% alcohol).

Most of the resin is used by the cosmetic and food industries. It has a sweet, light, nutty odor sometimes described as smelling like root beer, grape juice, or vanilla, with chocolate and almond-cherry undertones. In perfumery, it most often is used as a base note. It also has excellent fixative properties, especially for fragrance middle notes.

There are two main types of benzoin resin. Benzoin Sumatra, from S. benzoin primarily, with some from S. paralleoneurus, comes predominantly from Java and Sumatra. It contains cinnamic acid and has a smoky, woody, and incense aroma and is mostly used in pharmaceutical preparations. Its scent composition is cinnamic acid 20%, benzoic acid 18%, and vanillin 1%.
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Benzoin Siam, obtained from S. tonkinensis, is found across the highlands of Thailand, Laos, Cambodia, and Vietnam. It is mainly used for perfumery and food flavoring and has a sweet-balsamic aroma with a distinct note of vanilla. The Laotian resin is thought to be the best quality, with a velvety finish and pronounced fruity note. The chief constituent is benzoic acid 32%, with vanillin 2% but no cinnamic acid.
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Benzoin gives a luminous 'body' to perfumes. Highly versatile, benzoin is frequently used in amber and spicy Oriental fragrances and also complements citrus, woods (cypress, juniper, cedarwood, sandalwood, laurel), and florals (jasmine, lavender, rose, geranium). It mixes well with frankincense, myrrh, vetiver, and patchouli, and it has a special affinity for other sweet and rich notes like vanilla, leather, and tonka bean. It is used sparingly since its richness easily can overwhelm other ingredients. Says perfumer Alienor Massenet, "Benzoin is as suave as vanilla, and has a touch of cinnamon to it. I use it for feminine and masculine fragrances: it gives an 'openness' and sensuality to fragrances."
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The name probably is derived from the Arabic lubān jāwī (meaning 'Javan frankincense,' as it was called in the 14th century). At times it has colloquially been called benjamin or benjoin. Records from ancient Egypt indicate that benzoin was mixed with other aromatic resins like pine, juniper, cypress, galbanum, and labdanum to create an aromatic powder that dancers applied to their heads, and it was used in embalming and for incense. Herodotus of Halicarnassus indicates the in the 5th century BC different kinds of storax were traded.

There is some uncertainty about exactly which resins old written sources mention. Turkish sweetgum (Liquidambar orientalis), an unrelated tree in the family Altingiaceae, produces a similar resin now traded as storax or Levant storax, as do other sweetgums. Turkish sweetgum occurs only in a small area of southwest Turkey, not in the Levant at all. Presumably some of the 'storax resin' of ancient Greek and Roman sources was this sweetgum rather than a Styrax, although genuine Styrax resin (probably mainly from S. officinalis) was imported from the Near East by Phoenician merchants. Since the Middle Ages, Southeast Asian benzoin resins became increasingly available, and today there is very little international trade in S. officinalis and Turkish sweetgum resins.

In medicine benzoin has been used for millenia for arthritis and rheumatism, spasms, asthma, bronchitis and coughing (as a mild expectorant), sore throat and laryngitis, eczema and chapped skin, cuts, and bruises, and stress. Avicenna discusses S. officinalis in his Al-Qanun fi al-Tibb, indicating that the resin, mixed with other antibiotic substances and hardening material, makes a good dental restorative material. Benzoin resin is a component of the 'Theriaca Andromachi Senioris,' a Venic treacle recipe in the 1686 d'Amsterdammer Apotheek. It acts as a styptic, stopping minor bleeding, and an antiseptic; the antibiotic activity seems to be due mainly to benzoic acid and benzoic acid esters. Tincture of benzoin (also called friar's balsam), which is the resin dissolved in alcohol (approximately 20% resin and 80% alcohol), was invented around 1790 by Joshua Ward and was used in 19th century European antiseptic and cleaning preparations. It is commonly used now in first aid for small injuries, since it acts as a disinfectant and local anesthetic and may promote healing. The tincture also is a topical adhesive agent that is used to provide tackiness and enhance the sticking properties of medical tape, especially 'butterfly' bandages and tape over sutures (Steri-Strips). This is particularly helpful for facial areas. It has also been used as a preoperative antiseptic for wound preparation. Benzoin is used commonly in veterinary medicine.

After being blended with other oils, benzoin can be used to treat skin irritations such as itchiness, dryness, and inflammation. However, it can cause contact dermatitis, primarily due to its benzyl benzoate. There has been little modern research on the medical properties or safety of the resin.

In aromatherapy, although it is thought to be a mild stimulant, benzoin has a calming and grounding effect, providing a 'padded zone' between the user and external events. It is said to 'heal the wounds of the soul.'

Most benzoin is used in the Arab states of the Persian Gulf, Indonesia, India, and the horn of Africa, where it is burned for fragrance on charcoal grills. In the Middle East, an incense of scented wood chips called Bakhoor contains benzoin. Bakhoor is used on coal fires as an Arab outdoor air freshener. It is also used as incense in Roman Catholic, Orthodox Christian, and Greek Christian churches. The incense is mentioned in the Book of Exodus. Styrax was incorporated into Japanese, Indian, and Chinese incense, as well as in the European Papier d'Arménie, a paper strip burned indoors and still sold in small booklets. Although toxic benzene and formaldehyde are produced when Styrax incense is burned, a strip of Papier d'Arménie burned every 2-3 days produces less of them than do many modern synthetic air fresheners. Styrax resin from southern Arabian species was burned in fields during frankincense harvesting because it was thought to drive away poisonous snakes.

Several species of Styrax are popular as ornamental trees in parks and gardens. The wood of larger species is suitable for carving and handicrafts; wood of S. japonicus ('egonoki') is used to build Japanese bowed musical instruments.

The resin is used as a flavoring in foods (beverages, baked goods, chewing gum, frozen dairy, gelatins, puddings, soft candy) and medicines. Benzoin resin and its derivatives also are used in tobacco cigarettes as flavoring agents and to increase transmucosal nicotine absorption. It is used for scenting toothpastes, soaps, and other personal care products.

The chemical benzoin (2-hydroxy-2-phenylacetophenone) actually is not found in benzoin resin in measurable quantities at all. The resin does contain small amounts of the hydrocarbon styrene, named for the unrelated Levant storax from which it was first isolated. Industrially produced styrene is now used to make polystyrene plastics, including Styrofoam.

Synthetic chemicals are replacing real benzoin resin in some perfume products and are said to blend well with other fragrance materials. Marketed by several companies, they typically are called 'benzoin resin replacer.'

Perfume products for men with significant benzoin include:

Acqua di Parma Colonia Intensa
Annick Goutal Ambre Fetiche
Aramis JHL
Ashley Oud
Azzaro Elixir, Elixir Bois Precieux, Onyx
Baldessarini
Balenciaga Cristobal
Battistoni Marte Evolution
Boucheron Jaipur
Bvlgari Man (various), Aqva Atlantiqve
By Kilian Back to Black
Carolina Herrera Men Prive
Cesare Paciotti Oriental Supreme
Chanel Allure
Chris Adams MP
Christian Dior Feve Delicieuse
Comme des Garcons
Davidoff Silver Shadow, Relax, Hot Water
Diesel Only the Brave Tattoo
Diptyque Benjoin Boheme, Volutes
Elemi Incense with a Twist of Lemon
Francis Kurkdjian Oud Satin Mood, Grand Soir, Absolue pour le Soir
Franck Olivier Red
Giorgio Armani Myrrhe Imperiale, Code Absolu Gold
Giorgio Beverly Hills VIP Special Reserve, Giorgio
Givenchy Pi (various)
Goldfield & Banks Australia Desert Rosewood
Gucci Guilty
Guerlain Bois d'Armenie, Arsene Lupin Voyou, Habit Rouge, Coriolan
Halston Catalyst, Z
Hermes Terre d'Hermes (various), Rocabar
Hugo Boss Dark Blue
Imaginary Authors Memoirs of a Trespasser
Issey Miyake l'Eau d'Issey Intense
Jil Sander Man II
Karl Lagerfeld Photo, KL
Kenzo Jungle
Lancome Sagamore
Lanvin Avant Garde
Laura Biagiotti Roma
Leonard Cuir d'Ambre
L'Erbolario Dolcelisir
Marly Oajan
Mauboussin pour Lui in Black
M. Micallef Jadu SE
Nino Cerruti
O Boticario Coffee Duo, Malbec (various)
Pierre Balmain Carbone de Balmain, Ambre Gris
Prada Infusion
Prince Obolenski Russian Leather
Ralph Lauren Chaps
Serge Lutens Ambre Sultan
Thera Cosmeticos Urano
Thierry Mugler A*Men Pur Havane
Tom Ford Atelier d'Orient Plum Japonais
Trussardi Amber Oud
Van Cleef & Arpels Midnight in Paris
Versace Versus
Xerjoff Mamluk
Valentino Vendetta
Yves St. Laurent Body Kouros, Jazz Prestige
 
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